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2-(4-Sulfamoylphenyl)hydrazin-1-ium chloride
The hydrazinium residue in the cation of the title salt, C(6)H(10)N(3)O(2)S(+)·Cl(−), is twisted out of the plane of the benzene ring to which it is attached [N—N—C—C torsion angle = 25.9 (2)°] and the amino group is almost perpendicular to the benzene ring [N—S—C—C torsion angle = 88.71 (16)°]. In...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344085/ https://www.ncbi.nlm.nih.gov/pubmed/22606088 http://dx.doi.org/10.1107/S1600536812011452 |
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author | Asiri, Abdullah M. Faidallah, Hassan M. Alamry, Khalid A. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Asiri, Abdullah M. Faidallah, Hassan M. Alamry, Khalid A. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Asiri, Abdullah M. |
collection | PubMed |
description | The hydrazinium residue in the cation of the title salt, C(6)H(10)N(3)O(2)S(+)·Cl(−), is twisted out of the plane of the benzene ring to which it is attached [N—N—C—C torsion angle = 25.9 (2)°] and the amino group is almost perpendicular to the benzene ring [N—S—C—C torsion angle = 88.71 (16)°]. In the crystal, the cations are linked by N—H⋯O hydrogen bonds and π–π interactions [ring centroid distance = 3.7280 (11) Å], forming layers in the bc plane that are connected by N—H⋯Cl hydrogen bonds. |
format | Online Article Text |
id | pubmed-3344085 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33440852012-05-17 2-(4-Sulfamoylphenyl)hydrazin-1-ium chloride Asiri, Abdullah M. Faidallah, Hassan M. Alamry, Khalid A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The hydrazinium residue in the cation of the title salt, C(6)H(10)N(3)O(2)S(+)·Cl(−), is twisted out of the plane of the benzene ring to which it is attached [N—N—C—C torsion angle = 25.9 (2)°] and the amino group is almost perpendicular to the benzene ring [N—S—C—C torsion angle = 88.71 (16)°]. In the crystal, the cations are linked by N—H⋯O hydrogen bonds and π–π interactions [ring centroid distance = 3.7280 (11) Å], forming layers in the bc plane that are connected by N—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3344085/ /pubmed/22606088 http://dx.doi.org/10.1107/S1600536812011452 Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Asiri, Abdullah M. Faidallah, Hassan M. Alamry, Khalid A. Ng, Seik Weng Tiekink, Edward R. T. 2-(4-Sulfamoylphenyl)hydrazin-1-ium chloride |
title | 2-(4-Sulfamoylphenyl)hydrazin-1-ium chloride |
title_full | 2-(4-Sulfamoylphenyl)hydrazin-1-ium chloride |
title_fullStr | 2-(4-Sulfamoylphenyl)hydrazin-1-ium chloride |
title_full_unstemmed | 2-(4-Sulfamoylphenyl)hydrazin-1-ium chloride |
title_short | 2-(4-Sulfamoylphenyl)hydrazin-1-ium chloride |
title_sort | 2-(4-sulfamoylphenyl)hydrazin-1-ium chloride |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344085/ https://www.ncbi.nlm.nih.gov/pubmed/22606088 http://dx.doi.org/10.1107/S1600536812011452 |
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