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2-[N-(4-{4-[(2-Hydroxy-5-methoxybenzylidene)amino]benzyl}phenyl)carboximidoyl]-4-methoxyphenol
In the title Schiff base, C(29)H(26)N(2)O(4), the complete molecule is generated by a crystallographic twofold axis and is V-shaped. The planes of the benzene rings of the central diphenylmethane unit make a dihedral angle of 78.11 (4)° while adjacent benzene and 5-methoxysalicylidene rings are...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344086/ https://www.ncbi.nlm.nih.gov/pubmed/22606089 http://dx.doi.org/10.1107/S1600536812010550 |
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author | Ourari, Ali Baameur, Lotfi Bouet, Gilles Allain, Magali |
author_facet | Ourari, Ali Baameur, Lotfi Bouet, Gilles Allain, Magali |
author_sort | Ourari, Ali |
collection | PubMed |
description | In the title Schiff base, C(29)H(26)N(2)O(4), the complete molecule is generated by a crystallographic twofold axis and is V-shaped. The planes of the benzene rings of the central diphenylmethane unit make a dihedral angle of 78.11 (4)° while adjacent benzene and 5-methoxysalicylidene rings are twisted with respect to each other by a dihedral angle of 11.84 (8)°. The Schiff base is in the enol–imino form and an intramolecular O—H⋯N hydrogen bond is observed. |
format | Online Article Text |
id | pubmed-3344086 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33440862012-05-17 2-[N-(4-{4-[(2-Hydroxy-5-methoxybenzylidene)amino]benzyl}phenyl)carboximidoyl]-4-methoxyphenol Ourari, Ali Baameur, Lotfi Bouet, Gilles Allain, Magali Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base, C(29)H(26)N(2)O(4), the complete molecule is generated by a crystallographic twofold axis and is V-shaped. The planes of the benzene rings of the central diphenylmethane unit make a dihedral angle of 78.11 (4)° while adjacent benzene and 5-methoxysalicylidene rings are twisted with respect to each other by a dihedral angle of 11.84 (8)°. The Schiff base is in the enol–imino form and an intramolecular O—H⋯N hydrogen bond is observed. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344086/ /pubmed/22606089 http://dx.doi.org/10.1107/S1600536812010550 Text en © Ourari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ourari, Ali Baameur, Lotfi Bouet, Gilles Allain, Magali 2-[N-(4-{4-[(2-Hydroxy-5-methoxybenzylidene)amino]benzyl}phenyl)carboximidoyl]-4-methoxyphenol |
title | 2-[N-(4-{4-[(2-Hydroxy-5-methoxybenzylidene)amino]benzyl}phenyl)carboximidoyl]-4-methoxyphenol |
title_full | 2-[N-(4-{4-[(2-Hydroxy-5-methoxybenzylidene)amino]benzyl}phenyl)carboximidoyl]-4-methoxyphenol |
title_fullStr | 2-[N-(4-{4-[(2-Hydroxy-5-methoxybenzylidene)amino]benzyl}phenyl)carboximidoyl]-4-methoxyphenol |
title_full_unstemmed | 2-[N-(4-{4-[(2-Hydroxy-5-methoxybenzylidene)amino]benzyl}phenyl)carboximidoyl]-4-methoxyphenol |
title_short | 2-[N-(4-{4-[(2-Hydroxy-5-methoxybenzylidene)amino]benzyl}phenyl)carboximidoyl]-4-methoxyphenol |
title_sort | 2-[n-(4-{4-[(2-hydroxy-5-methoxybenzylidene)amino]benzyl}phenyl)carboximidoyl]-4-methoxyphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344086/ https://www.ncbi.nlm.nih.gov/pubmed/22606089 http://dx.doi.org/10.1107/S1600536812010550 |
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