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N′-[(1E,2E)-3,7-Dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide

In the title compound, C(16)H(21)N(3)O, the mol­ecule adopts an E conformation about the central C=N double bond. The 2-methyl­pent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. v...

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Detalles Bibliográficos
Autores principales: Bhat, Mashooq A., Abdel-Aziz, Hatem A., Ghabbour, Hazem A., Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344089/
https://www.ncbi.nlm.nih.gov/pubmed/22606092
http://dx.doi.org/10.1107/S1600536812009075
Descripción
Sumario:In the title compound, C(16)H(21)N(3)O, the mol­ecule adopts an E conformation about the central C=N double bond. The 2-methyl­pent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. value for the major component is 0.021 (7) and its maximum deviation is 0.025 (4) Å; the r.m.s. value for the minor component is 0.03 (4) and its maximum deviation is 0.05 (3) Å] major and minor components of the 2-methyl­but-2-ene group is 35.9 (13)°. In the crystal, C—H⋯O and N—H⋯O hydrogen bonds link the molecules, with the same O atom acting as the acceptor. This results in C (1) (1)(4) and C (1) (1)(5) [001] chains.