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N′-[(1E,2E)-3,7-Dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide

In the title compound, C(16)H(21)N(3)O, the mol­ecule adopts an E conformation about the central C=N double bond. The 2-methyl­pent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. v...

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Autores principales: Bhat, Mashooq A., Abdel-Aziz, Hatem A., Ghabbour, Hazem A., Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344089/
https://www.ncbi.nlm.nih.gov/pubmed/22606092
http://dx.doi.org/10.1107/S1600536812009075
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author Bhat, Mashooq A.
Abdel-Aziz, Hatem A.
Ghabbour, Hazem A.
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Bhat, Mashooq A.
Abdel-Aziz, Hatem A.
Ghabbour, Hazem A.
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Bhat, Mashooq A.
collection PubMed
description In the title compound, C(16)H(21)N(3)O, the mol­ecule adopts an E conformation about the central C=N double bond. The 2-methyl­pent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. value for the major component is 0.021 (7) and its maximum deviation is 0.025 (4) Å; the r.m.s. value for the minor component is 0.03 (4) and its maximum deviation is 0.05 (3) Å] major and minor components of the 2-methyl­but-2-ene group is 35.9 (13)°. In the crystal, C—H⋯O and N—H⋯O hydrogen bonds link the molecules, with the same O atom acting as the acceptor. This results in C (1) (1)(4) and C (1) (1)(5) [001] chains.
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spelling pubmed-33440892012-05-17 N′-[(1E,2E)-3,7-Dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide Bhat, Mashooq A. Abdel-Aziz, Hatem A. Ghabbour, Hazem A. Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(21)N(3)O, the mol­ecule adopts an E conformation about the central C=N double bond. The 2-methyl­pent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. value for the major component is 0.021 (7) and its maximum deviation is 0.025 (4) Å; the r.m.s. value for the minor component is 0.03 (4) and its maximum deviation is 0.05 (3) Å] major and minor components of the 2-methyl­but-2-ene group is 35.9 (13)°. In the crystal, C—H⋯O and N—H⋯O hydrogen bonds link the molecules, with the same O atom acting as the acceptor. This results in C (1) (1)(4) and C (1) (1)(5) [001] chains. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344089/ /pubmed/22606092 http://dx.doi.org/10.1107/S1600536812009075 Text en © Bhat et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bhat, Mashooq A.
Abdel-Aziz, Hatem A.
Ghabbour, Hazem A.
Hemamalini, Madhukar
Fun, Hoong-Kun
N′-[(1E,2E)-3,7-Dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide
title N′-[(1E,2E)-3,7-Dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide
title_full N′-[(1E,2E)-3,7-Dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide
title_fullStr N′-[(1E,2E)-3,7-Dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide
title_full_unstemmed N′-[(1E,2E)-3,7-Dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide
title_short N′-[(1E,2E)-3,7-Dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide
title_sort n′-[(1e,2e)-3,7-dimethyl­octa-2,6-dien-1-yl­idene]pyridine-4-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344089/
https://www.ncbi.nlm.nih.gov/pubmed/22606092
http://dx.doi.org/10.1107/S1600536812009075
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