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N′-[(1E,2E)-3,7-Dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide
In the title compound, C(16)H(21)N(3)O, the molecule adopts an E conformation about the central C=N double bond. The 2-methylpent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. v...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344089/ https://www.ncbi.nlm.nih.gov/pubmed/22606092 http://dx.doi.org/10.1107/S1600536812009075 |
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author | Bhat, Mashooq A. Abdel-Aziz, Hatem A. Ghabbour, Hazem A. Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Bhat, Mashooq A. Abdel-Aziz, Hatem A. Ghabbour, Hazem A. Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Bhat, Mashooq A. |
collection | PubMed |
description | In the title compound, C(16)H(21)N(3)O, the molecule adopts an E conformation about the central C=N double bond. The 2-methylpent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. value for the major component is 0.021 (7) and its maximum deviation is 0.025 (4) Å; the r.m.s. value for the minor component is 0.03 (4) and its maximum deviation is 0.05 (3) Å] major and minor components of the 2-methylbut-2-ene group is 35.9 (13)°. In the crystal, C—H⋯O and N—H⋯O hydrogen bonds link the molecules, with the same O atom acting as the acceptor. This results in C (1) (1)(4) and C (1) (1)(5) [001] chains. |
format | Online Article Text |
id | pubmed-3344089 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33440892012-05-17 N′-[(1E,2E)-3,7-Dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide Bhat, Mashooq A. Abdel-Aziz, Hatem A. Ghabbour, Hazem A. Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(21)N(3)O, the molecule adopts an E conformation about the central C=N double bond. The 2-methylpent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. value for the major component is 0.021 (7) and its maximum deviation is 0.025 (4) Å; the r.m.s. value for the minor component is 0.03 (4) and its maximum deviation is 0.05 (3) Å] major and minor components of the 2-methylbut-2-ene group is 35.9 (13)°. In the crystal, C—H⋯O and N—H⋯O hydrogen bonds link the molecules, with the same O atom acting as the acceptor. This results in C (1) (1)(4) and C (1) (1)(5) [001] chains. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344089/ /pubmed/22606092 http://dx.doi.org/10.1107/S1600536812009075 Text en © Bhat et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bhat, Mashooq A. Abdel-Aziz, Hatem A. Ghabbour, Hazem A. Hemamalini, Madhukar Fun, Hoong-Kun N′-[(1E,2E)-3,7-Dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide |
title |
N′-[(1E,2E)-3,7-Dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide |
title_full |
N′-[(1E,2E)-3,7-Dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide |
title_fullStr |
N′-[(1E,2E)-3,7-Dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide |
title_full_unstemmed |
N′-[(1E,2E)-3,7-Dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide |
title_short |
N′-[(1E,2E)-3,7-Dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide |
title_sort | n′-[(1e,2e)-3,7-dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344089/ https://www.ncbi.nlm.nih.gov/pubmed/22606092 http://dx.doi.org/10.1107/S1600536812009075 |
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