2-Amino-6-{[(6-chloropyridin-3-yl)methyl](ethyl)amino}-1-methyl-5-nitro-4-phenyl-1,4-dihydro­pyridine-3-carbonitrile ethanol monosolvate

In the title compound, C(21)H(21)ClN(6)O(2)·C(2)H(6)O, a member of the insecticidal active neonicotinoid group of compounds, the 1,4-dihydro­pyridine ring adopts a boat conformation. An intra­molecular C—H⋯O hydrogen bond occurs while the components are linked by an N—H⋯O interaction. The crystal pa...

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Detalles Bibliográficos
Autores principales: Sun, Chuan-Wen, Chen, Yan-Xia, Liu, Tian-Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344090/
https://www.ncbi.nlm.nih.gov/pubmed/22606093
http://dx.doi.org/10.1107/S1600536812011750
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author Sun, Chuan-Wen
Chen, Yan-Xia
Liu, Tian-Yan
author_facet Sun, Chuan-Wen
Chen, Yan-Xia
Liu, Tian-Yan
author_sort Sun, Chuan-Wen
collection PubMed
description In the title compound, C(21)H(21)ClN(6)O(2)·C(2)H(6)O, a member of the insecticidal active neonicotinoid group of compounds, the 1,4-dihydro­pyridine ring adopts a boat conformation. An intra­molecular C—H⋯O hydrogen bond occurs while the components are linked by an N—H⋯O interaction. The crystal packing is stablized by O—H⋯N hydrogen bonds and C—H⋯O interactions.
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spelling pubmed-33440902012-05-17 2-Amino-6-{[(6-chloropyridin-3-yl)methyl](ethyl)amino}-1-methyl-5-nitro-4-phenyl-1,4-dihydro­pyridine-3-carbonitrile ethanol monosolvate Sun, Chuan-Wen Chen, Yan-Xia Liu, Tian-Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(21)ClN(6)O(2)·C(2)H(6)O, a member of the insecticidal active neonicotinoid group of compounds, the 1,4-dihydro­pyridine ring adopts a boat conformation. An intra­molecular C—H⋯O hydrogen bond occurs while the components are linked by an N—H⋯O interaction. The crystal packing is stablized by O—H⋯N hydrogen bonds and C—H⋯O interactions. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344090/ /pubmed/22606093 http://dx.doi.org/10.1107/S1600536812011750 Text en © Sun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Chuan-Wen
Chen, Yan-Xia
Liu, Tian-Yan
2-Amino-6-{[(6-chloropyridin-3-yl)methyl](ethyl)amino}-1-methyl-5-nitro-4-phenyl-1,4-dihydro­pyridine-3-carbonitrile ethanol monosolvate
title 2-Amino-6-{[(6-chloropyridin-3-yl)methyl](ethyl)amino}-1-methyl-5-nitro-4-phenyl-1,4-dihydro­pyridine-3-carbonitrile ethanol monosolvate
title_full 2-Amino-6-{[(6-chloropyridin-3-yl)methyl](ethyl)amino}-1-methyl-5-nitro-4-phenyl-1,4-dihydro­pyridine-3-carbonitrile ethanol monosolvate
title_fullStr 2-Amino-6-{[(6-chloropyridin-3-yl)methyl](ethyl)amino}-1-methyl-5-nitro-4-phenyl-1,4-dihydro­pyridine-3-carbonitrile ethanol monosolvate
title_full_unstemmed 2-Amino-6-{[(6-chloropyridin-3-yl)methyl](ethyl)amino}-1-methyl-5-nitro-4-phenyl-1,4-dihydro­pyridine-3-carbonitrile ethanol monosolvate
title_short 2-Amino-6-{[(6-chloropyridin-3-yl)methyl](ethyl)amino}-1-methyl-5-nitro-4-phenyl-1,4-dihydro­pyridine-3-carbonitrile ethanol monosolvate
title_sort 2-amino-6-{[(6-chloropyridin-3-yl)methyl](ethyl)amino}-1-methyl-5-nitro-4-phenyl-1,4-dihydro­pyridine-3-carbonitrile ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344090/
https://www.ncbi.nlm.nih.gov/pubmed/22606093
http://dx.doi.org/10.1107/S1600536812011750
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AT chenyanxia 2amino66chloropyridin3ylmethylethylamino1methyl5nitro4phenyl14dihydropyridine3carbonitrileethanolmonosolvate
AT liutianyan 2amino66chloropyridin3ylmethylethylamino1methyl5nitro4phenyl14dihydropyridine3carbonitrileethanolmonosolvate

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