Methyl 2,2-dimeth­oxy-8-oxo-1-oxaspiro­[4.5]deca-6,9-diene-3-carboxyl­ate

In the title mol­ecule, C(13)H(16)O(6), the cyclo­hexa-1,4-diene ring adopts a flat boat conformation (r.m.s. deviation from planarity = 0.060 Å) and the five-membered tetra­hydro­furan ring adopts an envelope conformation with the carboxyl group-substituted C atom as the flap. The dihedral angle at...

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Detalles Bibliográficos
Autor principal: Lou, Yongbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344095/
https://www.ncbi.nlm.nih.gov/pubmed/22606098
http://dx.doi.org/10.1107/S1600536812011737
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author Lou, Yongbing
author_facet Lou, Yongbing
author_sort Lou, Yongbing
collection PubMed
description In the title mol­ecule, C(13)H(16)O(6), the cyclo­hexa-1,4-diene ring adopts a flat boat conformation (r.m.s. deviation from planarity = 0.060 Å) and the five-membered tetra­hydro­furan ring adopts an envelope conformation with the carboxyl group-substituted C atom as the flap. The dihedral angle at the spiro junction is 89.1 (1)°. In the crystal, mol­ecules are linked through weak C—H⋯O and van der Waals inter­actions.
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spelling pubmed-33440952012-05-17 Methyl 2,2-dimeth­oxy-8-oxo-1-oxaspiro­[4.5]deca-6,9-diene-3-carboxyl­ate Lou, Yongbing Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(13)H(16)O(6), the cyclo­hexa-1,4-diene ring adopts a flat boat conformation (r.m.s. deviation from planarity = 0.060 Å) and the five-membered tetra­hydro­furan ring adopts an envelope conformation with the carboxyl group-substituted C atom as the flap. The dihedral angle at the spiro junction is 89.1 (1)°. In the crystal, mol­ecules are linked through weak C—H⋯O and van der Waals inter­actions. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344095/ /pubmed/22606098 http://dx.doi.org/10.1107/S1600536812011737 Text en © Yongbing Lou 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lou, Yongbing
Methyl 2,2-dimeth­oxy-8-oxo-1-oxaspiro­[4.5]deca-6,9-diene-3-carboxyl­ate
title Methyl 2,2-dimeth­oxy-8-oxo-1-oxaspiro­[4.5]deca-6,9-diene-3-carboxyl­ate
title_full Methyl 2,2-dimeth­oxy-8-oxo-1-oxaspiro­[4.5]deca-6,9-diene-3-carboxyl­ate
title_fullStr Methyl 2,2-dimeth­oxy-8-oxo-1-oxaspiro­[4.5]deca-6,9-diene-3-carboxyl­ate
title_full_unstemmed Methyl 2,2-dimeth­oxy-8-oxo-1-oxaspiro­[4.5]deca-6,9-diene-3-carboxyl­ate
title_short Methyl 2,2-dimeth­oxy-8-oxo-1-oxaspiro­[4.5]deca-6,9-diene-3-carboxyl­ate
title_sort methyl 2,2-dimeth­oxy-8-oxo-1-oxaspiro­[4.5]deca-6,9-diene-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344095/
https://www.ncbi.nlm.nih.gov/pubmed/22606098
http://dx.doi.org/10.1107/S1600536812011737
work_keys_str_mv AT louyongbing methyl22dimethoxy8oxo1oxaspiro45deca69diene3carboxylate

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