1-[(2S)-1-Chloro-3-phenyl­propan-2-yl]-2,4,5-triphenyl-1H-imidazole

In the title compound, C(30)H(25)ClN(2), the chiral center maintains the S configuration of the stating l-phenyl­alaninol. The two phenyl groups closest to the substituted N atom adopt an almost perpendicular orientation relative to the central imidazole ring, with dihedral angles of 88.9 (4) and 84...

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Detalles Bibliográficos
Autores principales: Xiao, Yongmei, Yang, Liangru, He, Kun, Yuan, Jinwei, Mao, Pu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344096/
https://www.ncbi.nlm.nih.gov/pubmed/22606099
http://dx.doi.org/10.1107/S1600536812009609
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author Xiao, Yongmei
Yang, Liangru
He, Kun
Yuan, Jinwei
Mao, Pu
author_facet Xiao, Yongmei
Yang, Liangru
He, Kun
Yuan, Jinwei
Mao, Pu
author_sort Xiao, Yongmei
collection PubMed
description In the title compound, C(30)H(25)ClN(2), the chiral center maintains the S configuration of the stating l-phenyl­alaninol. The two phenyl groups closest to the substituted N atom adopt an almost perpendicular orientation relative to the central imidazole ring, with dihedral angles of 88.9 (4) and 84.7 (3)°. The third phenyl group is nearly coplanar with it, making a dihedral angle of 11.0 (5)°.
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spelling pubmed-33440962012-05-17 1-[(2S)-1-Chloro-3-phenyl­propan-2-yl]-2,4,5-triphenyl-1H-imidazole Xiao, Yongmei Yang, Liangru He, Kun Yuan, Jinwei Mao, Pu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(25)ClN(2), the chiral center maintains the S configuration of the stating l-phenyl­alaninol. The two phenyl groups closest to the substituted N atom adopt an almost perpendicular orientation relative to the central imidazole ring, with dihedral angles of 88.9 (4) and 84.7 (3)°. The third phenyl group is nearly coplanar with it, making a dihedral angle of 11.0 (5)°. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344096/ /pubmed/22606099 http://dx.doi.org/10.1107/S1600536812009609 Text en © Xiao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xiao, Yongmei
Yang, Liangru
He, Kun
Yuan, Jinwei
Mao, Pu
1-[(2S)-1-Chloro-3-phenyl­propan-2-yl]-2,4,5-triphenyl-1H-imidazole
title 1-[(2S)-1-Chloro-3-phenyl­propan-2-yl]-2,4,5-triphenyl-1H-imidazole
title_full 1-[(2S)-1-Chloro-3-phenyl­propan-2-yl]-2,4,5-triphenyl-1H-imidazole
title_fullStr 1-[(2S)-1-Chloro-3-phenyl­propan-2-yl]-2,4,5-triphenyl-1H-imidazole
title_full_unstemmed 1-[(2S)-1-Chloro-3-phenyl­propan-2-yl]-2,4,5-triphenyl-1H-imidazole
title_short 1-[(2S)-1-Chloro-3-phenyl­propan-2-yl]-2,4,5-triphenyl-1H-imidazole
title_sort 1-[(2s)-1-chloro-3-phenyl­propan-2-yl]-2,4,5-triphenyl-1h-imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344096/
https://www.ncbi.nlm.nih.gov/pubmed/22606099
http://dx.doi.org/10.1107/S1600536812009609
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