3-Acetyl-1-(2-methylphenyl)thiourea

In the title compound, C(10)H(12)N(2)OS, the toluene and the N-carbamothio­ylacetamide units are oriented at dihedral angle of 78.75 (5)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked into [101] chains by pairs of N—H⋯S hydrogen bonds [which ge...

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Autores principales: Shahwar, Durre, Tahir, M. Nawaz, Chohan, Muhammad Mansha, Ahmad, Naeem, Raza, M. Asam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344102/
https://www.ncbi.nlm.nih.gov/pubmed/22606105
http://dx.doi.org/10.1107/S1600536812011658
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author Shahwar, Durre
Tahir, M. Nawaz
Chohan, Muhammad Mansha
Ahmad, Naeem
Raza, M. Asam
author_facet Shahwar, Durre
Tahir, M. Nawaz
Chohan, Muhammad Mansha
Ahmad, Naeem
Raza, M. Asam
author_sort Shahwar, Durre
collection PubMed
description In the title compound, C(10)H(12)N(2)OS, the toluene and the N-carbamothio­ylacetamide units are oriented at dihedral angle of 78.75 (5)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked into [101] chains by pairs of N—H⋯S hydrogen bonds [which generate R (2) (2)(8) loops] and pairs of O—H⋯O hydrogen bonds [which generate R (2) (2)(4) loops]. The two motifs alternate in the chain.
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spelling pubmed-33441022012-05-17 3-Acetyl-1-(2-methylphenyl)thiourea Shahwar, Durre Tahir, M. Nawaz Chohan, Muhammad Mansha Ahmad, Naeem Raza, M. Asam Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(12)N(2)OS, the toluene and the N-carbamothio­ylacetamide units are oriented at dihedral angle of 78.75 (5)°. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked into [101] chains by pairs of N—H⋯S hydrogen bonds [which generate R (2) (2)(8) loops] and pairs of O—H⋯O hydrogen bonds [which generate R (2) (2)(4) loops]. The two motifs alternate in the chain. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344102/ /pubmed/22606105 http://dx.doi.org/10.1107/S1600536812011658 Text en © Shahwar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shahwar, Durre
Tahir, M. Nawaz
Chohan, Muhammad Mansha
Ahmad, Naeem
Raza, M. Asam
3-Acetyl-1-(2-methylphenyl)thiourea
title 3-Acetyl-1-(2-methylphenyl)thiourea
title_full 3-Acetyl-1-(2-methylphenyl)thiourea
title_fullStr 3-Acetyl-1-(2-methylphenyl)thiourea
title_full_unstemmed 3-Acetyl-1-(2-methylphenyl)thiourea
title_short 3-Acetyl-1-(2-methylphenyl)thiourea
title_sort 3-acetyl-1-(2-methylphenyl)thiourea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344102/
https://www.ncbi.nlm.nih.gov/pubmed/22606105
http://dx.doi.org/10.1107/S1600536812011658
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AT tahirmnawaz 3acetyl12methylphenylthiourea
AT chohanmuhammadmansha 3acetyl12methylphenylthiourea
AT ahmadnaeem 3acetyl12methylphenylthiourea
AT razamasam 3acetyl12methylphenylthiourea

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