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2-[(1-Methyl-1H-pyrrol-2-yl)methylidene]propanedinitrile
In the title compound, C(9)H(7)N(3), the N-bound methyl group and vinyl H atom are syn. The 12 non-H atoms comprising the molecule are essentially coplanar (r.m.s. deviation = 0.071 Å). Supramolecular tapes feature in the crystal packing, orientated perpendicular to [10-1], and are formed by C—H⋯N...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344110/ https://www.ncbi.nlm.nih.gov/pubmed/22606113 http://dx.doi.org/10.1107/S160053681201197X |
Sumario: | In the title compound, C(9)H(7)N(3), the N-bound methyl group and vinyl H atom are syn. The 12 non-H atoms comprising the molecule are essentially coplanar (r.m.s. deviation = 0.071 Å). Supramolecular tapes feature in the crystal packing, orientated perpendicular to [10-1], and are formed by C—H⋯N interactions involving each cyano N atom. The tapes are connected into layers via π–π interactions occurring between translationally related pyrrole rings [ring centroid–centroid distance = 3.8754 (10) Å]; the layers stack along the b axis. |
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