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2-[(1-Methyl-1H-pyrrol-2-yl)methylidene]propanedinitrile
In the title compound, C(9)H(7)N(3), the N-bound methyl group and vinyl H atom are syn. The 12 non-H atoms comprising the molecule are essentially coplanar (r.m.s. deviation = 0.071 Å). Supramolecular tapes feature in the crystal packing, orientated perpendicular to [10-1], and are formed by C—H⋯N...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344110/ https://www.ncbi.nlm.nih.gov/pubmed/22606113 http://dx.doi.org/10.1107/S160053681201197X |
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author | Asiri, Abdullah M. Faidallah, Hassan M. Al-Thabaiti, Shaeel A. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Asiri, Abdullah M. Faidallah, Hassan M. Al-Thabaiti, Shaeel A. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Asiri, Abdullah M. |
collection | PubMed |
description | In the title compound, C(9)H(7)N(3), the N-bound methyl group and vinyl H atom are syn. The 12 non-H atoms comprising the molecule are essentially coplanar (r.m.s. deviation = 0.071 Å). Supramolecular tapes feature in the crystal packing, orientated perpendicular to [10-1], and are formed by C—H⋯N interactions involving each cyano N atom. The tapes are connected into layers via π–π interactions occurring between translationally related pyrrole rings [ring centroid–centroid distance = 3.8754 (10) Å]; the layers stack along the b axis. |
format | Online Article Text |
id | pubmed-3344110 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33441102012-05-17 2-[(1-Methyl-1H-pyrrol-2-yl)methylidene]propanedinitrile Asiri, Abdullah M. Faidallah, Hassan M. Al-Thabaiti, Shaeel A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(7)N(3), the N-bound methyl group and vinyl H atom are syn. The 12 non-H atoms comprising the molecule are essentially coplanar (r.m.s. deviation = 0.071 Å). Supramolecular tapes feature in the crystal packing, orientated perpendicular to [10-1], and are formed by C—H⋯N interactions involving each cyano N atom. The tapes are connected into layers via π–π interactions occurring between translationally related pyrrole rings [ring centroid–centroid distance = 3.8754 (10) Å]; the layers stack along the b axis. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344110/ /pubmed/22606113 http://dx.doi.org/10.1107/S160053681201197X Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Asiri, Abdullah M. Faidallah, Hassan M. Al-Thabaiti, Shaeel A. Ng, Seik Weng Tiekink, Edward R. T. 2-[(1-Methyl-1H-pyrrol-2-yl)methylidene]propanedinitrile |
title | 2-[(1-Methyl-1H-pyrrol-2-yl)methylidene]propanedinitrile |
title_full | 2-[(1-Methyl-1H-pyrrol-2-yl)methylidene]propanedinitrile |
title_fullStr | 2-[(1-Methyl-1H-pyrrol-2-yl)methylidene]propanedinitrile |
title_full_unstemmed | 2-[(1-Methyl-1H-pyrrol-2-yl)methylidene]propanedinitrile |
title_short | 2-[(1-Methyl-1H-pyrrol-2-yl)methylidene]propanedinitrile |
title_sort | 2-[(1-methyl-1h-pyrrol-2-yl)methylidene]propanedinitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344110/ https://www.ncbi.nlm.nih.gov/pubmed/22606113 http://dx.doi.org/10.1107/S160053681201197X |
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