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2-[(1-Methyl-1H-pyrrol-2-yl)methyl­idene]propane­dinitrile

In the title compound, C(9)H(7)N(3), the N-bound methyl group and vinyl H atom are syn. The 12 non-H atoms comprising the mol­ecule are essentially coplanar (r.m.s. deviation = 0.071 Å). Supra­molecular tapes feature in the crystal packing, orientated perpendicular to [10-1], and are formed by C—H⋯N...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Faidallah, Hassan M., Al-Thabaiti, Shaeel A., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344110/
https://www.ncbi.nlm.nih.gov/pubmed/22606113
http://dx.doi.org/10.1107/S160053681201197X
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author Asiri, Abdullah M.
Faidallah, Hassan M.
Al-Thabaiti, Shaeel A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Asiri, Abdullah M.
Faidallah, Hassan M.
Al-Thabaiti, Shaeel A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Asiri, Abdullah M.
collection PubMed
description In the title compound, C(9)H(7)N(3), the N-bound methyl group and vinyl H atom are syn. The 12 non-H atoms comprising the mol­ecule are essentially coplanar (r.m.s. deviation = 0.071 Å). Supra­molecular tapes feature in the crystal packing, orientated perpendicular to [10-1], and are formed by C—H⋯N inter­actions involving each cyano N atom. The tapes are connected into layers via π–π inter­actions occurring between translationally related pyrrole rings [ring centroid–centroid distance = 3.8754 (10) Å]; the layers stack along the b axis.
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spelling pubmed-33441102012-05-17 2-[(1-Methyl-1H-pyrrol-2-yl)methyl­idene]propane­dinitrile Asiri, Abdullah M. Faidallah, Hassan M. Al-Thabaiti, Shaeel A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(7)N(3), the N-bound methyl group and vinyl H atom are syn. The 12 non-H atoms comprising the mol­ecule are essentially coplanar (r.m.s. deviation = 0.071 Å). Supra­molecular tapes feature in the crystal packing, orientated perpendicular to [10-1], and are formed by C—H⋯N inter­actions involving each cyano N atom. The tapes are connected into layers via π–π inter­actions occurring between translationally related pyrrole rings [ring centroid–centroid distance = 3.8754 (10) Å]; the layers stack along the b axis. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344110/ /pubmed/22606113 http://dx.doi.org/10.1107/S160053681201197X Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah M.
Faidallah, Hassan M.
Al-Thabaiti, Shaeel A.
Ng, Seik Weng
Tiekink, Edward R. T.
2-[(1-Methyl-1H-pyrrol-2-yl)methyl­idene]propane­dinitrile
title 2-[(1-Methyl-1H-pyrrol-2-yl)methyl­idene]propane­dinitrile
title_full 2-[(1-Methyl-1H-pyrrol-2-yl)methyl­idene]propane­dinitrile
title_fullStr 2-[(1-Methyl-1H-pyrrol-2-yl)methyl­idene]propane­dinitrile
title_full_unstemmed 2-[(1-Methyl-1H-pyrrol-2-yl)methyl­idene]propane­dinitrile
title_short 2-[(1-Methyl-1H-pyrrol-2-yl)methyl­idene]propane­dinitrile
title_sort 2-[(1-methyl-1h-pyrrol-2-yl)methyl­idene]propane­dinitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344110/
https://www.ncbi.nlm.nih.gov/pubmed/22606113
http://dx.doi.org/10.1107/S160053681201197X
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