6,6′-Dimeth­oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate

In the title compound, C(25)H(26)N(2)O(4)·CHCl(3), the aromatic rings of the imino­methyl-6-meth­oxy­phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol­ecular conformation is stabilized by intra­molecular O—H⋯N hydrogen bonds. In the crystal, an...

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Autores principales: Bahron, Hadariah, Bakar, Najihah Abu, Yamin, Bohari M., Yusof, M. Sukeri M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344115/
https://www.ncbi.nlm.nih.gov/pubmed/22606118
http://dx.doi.org/10.1107/S1600536812011531
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author Bahron, Hadariah
Bakar, Najihah Abu
Yamin, Bohari M.
Yusof, M. Sukeri M.
author_facet Bahron, Hadariah
Bakar, Najihah Abu
Yamin, Bohari M.
Yusof, M. Sukeri M.
author_sort Bahron, Hadariah
collection PubMed
description In the title compound, C(25)H(26)N(2)O(4)·CHCl(3), the aromatic rings of the imino­methyl-6-meth­oxy­phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol­ecular conformation is stabilized by intra­molecular O—H⋯N hydrogen bonds. In the crystal, an inter­molecular C—H⋯O hydrogen bond involving the chloro­form solvent mol­ecule is observed. The crystal packing is further stabilized by π–π stacking inter­actions [centroid–centroid distances = 3.739 (3)–3.776 (3) Å] between the benzene rings of centrosymmetrically related mol­ecules.
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spelling pubmed-33441152012-05-17 6,6′-Dimeth­oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate Bahron, Hadariah Bakar, Najihah Abu Yamin, Bohari M. Yusof, M. Sukeri M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(26)N(2)O(4)·CHCl(3), the aromatic rings of the imino­methyl-6-meth­oxy­phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol­ecular conformation is stabilized by intra­molecular O—H⋯N hydrogen bonds. In the crystal, an inter­molecular C—H⋯O hydrogen bond involving the chloro­form solvent mol­ecule is observed. The crystal packing is further stabilized by π–π stacking inter­actions [centroid–centroid distances = 3.739 (3)–3.776 (3) Å] between the benzene rings of centrosymmetrically related mol­ecules. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344115/ /pubmed/22606118 http://dx.doi.org/10.1107/S1600536812011531 Text en © Bahron et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bahron, Hadariah
Bakar, Najihah Abu
Yamin, Bohari M.
Yusof, M. Sukeri M.
6,6′-Dimeth­oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate
title 6,6′-Dimeth­oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate
title_full 6,6′-Dimeth­oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate
title_fullStr 6,6′-Dimeth­oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate
title_full_unstemmed 6,6′-Dimeth­oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate
title_short 6,6′-Dimeth­oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate
title_sort 6,6′-dimeth­oxy-2,2′-[(e,e′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344115/
https://www.ncbi.nlm.nih.gov/pubmed/22606118
http://dx.doi.org/10.1107/S1600536812011531
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