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N-Acetyl-N-[2,4-dicyano-1-(4-methoxyphenyl)-9,10-dihydrophenanthren-3-yl]acetamide
In the title compound, C(27)H(21)N(3)O(3), the cyclohexa-1,3-diene ring has a screw-boat conformation, and the fused ring system is folded, the dihedral angle between the outer benzene rings being 27.61 (6)°. The N-acetylacetamide residue (r.m.s. deviation = 0.0935 Å) has an anti conformation and...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344116/ https://www.ncbi.nlm.nih.gov/pubmed/22606119 http://dx.doi.org/10.1107/S160053681201210X |
| _version_ | 1782231919386165248 |
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| author | Asiri, Abdullah M. Faidallah, Hassan M. Al-Thabaiti, Shaeel A. Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Asiri, Abdullah M. Faidallah, Hassan M. Al-Thabaiti, Shaeel A. Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Asiri, Abdullah M. |
| collection | PubMed |
| description | In the title compound, C(27)H(21)N(3)O(3), the cyclohexa-1,3-diene ring has a screw-boat conformation, and the fused ring system is folded, the dihedral angle between the outer benzene rings being 27.61 (6)°. The N-acetylacetamide residue (r.m.s. deviation = 0.0935 Å) has an anti conformation and is essentially perpendicular to the benzene ring to which it is connected [dihedral angle = 89.14 (6)°]; the methoxybenzene group is also twisted out of this ring [dihedral angle = 59.47 (7)°]. The three-dimensional architecture is consolidated by C—H⋯O and C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-3344116 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33441162012-05-17 N-Acetyl-N-[2,4-dicyano-1-(4-methoxyphenyl)-9,10-dihydrophenanthren-3-yl]acetamide Asiri, Abdullah M. Faidallah, Hassan M. Al-Thabaiti, Shaeel A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(21)N(3)O(3), the cyclohexa-1,3-diene ring has a screw-boat conformation, and the fused ring system is folded, the dihedral angle between the outer benzene rings being 27.61 (6)°. The N-acetylacetamide residue (r.m.s. deviation = 0.0935 Å) has an anti conformation and is essentially perpendicular to the benzene ring to which it is connected [dihedral angle = 89.14 (6)°]; the methoxybenzene group is also twisted out of this ring [dihedral angle = 59.47 (7)°]. The three-dimensional architecture is consolidated by C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344116/ /pubmed/22606119 http://dx.doi.org/10.1107/S160053681201210X Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Asiri, Abdullah M. Faidallah, Hassan M. Al-Thabaiti, Shaeel A. Ng, Seik Weng Tiekink, Edward R. T. N-Acetyl-N-[2,4-dicyano-1-(4-methoxyphenyl)-9,10-dihydrophenanthren-3-yl]acetamide |
| title |
N-Acetyl-N-[2,4-dicyano-1-(4-methoxyphenyl)-9,10-dihydrophenanthren-3-yl]acetamide |
| title_full |
N-Acetyl-N-[2,4-dicyano-1-(4-methoxyphenyl)-9,10-dihydrophenanthren-3-yl]acetamide |
| title_fullStr |
N-Acetyl-N-[2,4-dicyano-1-(4-methoxyphenyl)-9,10-dihydrophenanthren-3-yl]acetamide |
| title_full_unstemmed |
N-Acetyl-N-[2,4-dicyano-1-(4-methoxyphenyl)-9,10-dihydrophenanthren-3-yl]acetamide |
| title_short |
N-Acetyl-N-[2,4-dicyano-1-(4-methoxyphenyl)-9,10-dihydrophenanthren-3-yl]acetamide |
| title_sort | n-acetyl-n-[2,4-dicyano-1-(4-methoxyphenyl)-9,10-dihydrophenanthren-3-yl]acetamide |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344116/ https://www.ncbi.nlm.nih.gov/pubmed/22606119 http://dx.doi.org/10.1107/S160053681201210X |
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