5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate

In the title hydrated salt, C(16)H(38)N(4) (2+)·2ClO(4) (−)·H(2)O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH(3))(2)– groups. Within the cavity, there are two ammonium–amine N—H⋯N hydrogen bonds. Supra­molecular layers are formed in the crystal packing where...

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Detalles Bibliográficos
Autores principales: Hazari, Saroj K. S., Roy, Tapashi G., Nath, Babul Chandra, Roy, Prashun G., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344117/
https://www.ncbi.nlm.nih.gov/pubmed/22606120
http://dx.doi.org/10.1107/S1600536812012135
Descripción
Sumario:In the title hydrated salt, C(16)H(38)N(4) (2+)·2ClO(4) (−)·H(2)O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH(3))(2)– groups. Within the cavity, there are two ammonium–amine N—H⋯N hydrogen bonds. Supra­molecular layers are formed in the crystal packing whereby the water mol­ecule links two perchlorate anions, and the resultant aggregates are connected to the dications via N—H⋯O hydrogen bonds. Layers, with an undulating topology, stack along the a axis being connected by C—H⋯O inter­actions.

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