5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate

In the title hydrated salt, C(16)H(38)N(4) (2+)·2ClO(4) (−)·H(2)O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH(3))(2)– groups. Within the cavity, there are two ammonium–amine N—H⋯N hydrogen bonds. Supra­molecular layers are formed in the crystal packing where...

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Autores principales: Hazari, Saroj K. S., Roy, Tapashi G., Nath, Babul Chandra, Roy, Prashun G., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344117/
https://www.ncbi.nlm.nih.gov/pubmed/22606120
http://dx.doi.org/10.1107/S1600536812012135
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author Hazari, Saroj K. S.
Roy, Tapashi G.
Nath, Babul Chandra
Roy, Prashun G.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Hazari, Saroj K. S.
Roy, Tapashi G.
Nath, Babul Chandra
Roy, Prashun G.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Hazari, Saroj K. S.
collection PubMed
description In the title hydrated salt, C(16)H(38)N(4) (2+)·2ClO(4) (−)·H(2)O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH(3))(2)– groups. Within the cavity, there are two ammonium–amine N—H⋯N hydrogen bonds. Supra­molecular layers are formed in the crystal packing whereby the water mol­ecule links two perchlorate anions, and the resultant aggregates are connected to the dications via N—H⋯O hydrogen bonds. Layers, with an undulating topology, stack along the a axis being connected by C—H⋯O inter­actions.
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spelling pubmed-33441172012-05-17 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate Hazari, Saroj K. S. Roy, Tapashi G. Nath, Babul Chandra Roy, Prashun G. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated salt, C(16)H(38)N(4) (2+)·2ClO(4) (−)·H(2)O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH(3))(2)– groups. Within the cavity, there are two ammonium–amine N—H⋯N hydrogen bonds. Supra­molecular layers are formed in the crystal packing whereby the water mol­ecule links two perchlorate anions, and the resultant aggregates are connected to the dications via N—H⋯O hydrogen bonds. Layers, with an undulating topology, stack along the a axis being connected by C—H⋯O inter­actions. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344117/ /pubmed/22606120 http://dx.doi.org/10.1107/S1600536812012135 Text en © Hazari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hazari, Saroj K. S.
Roy, Tapashi G.
Nath, Babul Chandra
Roy, Prashun G.
Ng, Seik Weng
Tiekink, Edward R. T.
5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate
title 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate
title_full 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate
title_fullStr 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate
title_full_unstemmed 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate
title_short 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate
title_sort 5,7,7,12,14,14-hexamethyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344117/
https://www.ncbi.nlm.nih.gov/pubmed/22606120
http://dx.doi.org/10.1107/S1600536812012135
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