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5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate
In the title hydrated salt, C(16)H(38)N(4) (2+)·2ClO(4) (−)·H(2)O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH(3))(2)– groups. Within the cavity, there are two ammonium–amine N—H⋯N hydrogen bonds. Supramolecular layers are formed in the crystal packing where...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344117/ https://www.ncbi.nlm.nih.gov/pubmed/22606120 http://dx.doi.org/10.1107/S1600536812012135 |
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author | Hazari, Saroj K. S. Roy, Tapashi G. Nath, Babul Chandra Roy, Prashun G. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Hazari, Saroj K. S. Roy, Tapashi G. Nath, Babul Chandra Roy, Prashun G. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Hazari, Saroj K. S. |
collection | PubMed |
description | In the title hydrated salt, C(16)H(38)N(4) (2+)·2ClO(4) (−)·H(2)O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH(3))(2)– groups. Within the cavity, there are two ammonium–amine N—H⋯N hydrogen bonds. Supramolecular layers are formed in the crystal packing whereby the water molecule links two perchlorate anions, and the resultant aggregates are connected to the dications via N—H⋯O hydrogen bonds. Layers, with an undulating topology, stack along the a axis being connected by C—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3344117 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33441172012-05-17 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate Hazari, Saroj K. S. Roy, Tapashi G. Nath, Babul Chandra Roy, Prashun G. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated salt, C(16)H(38)N(4) (2+)·2ClO(4) (−)·H(2)O, the dication is protonated at the diagonally opposite N atoms proximate to the –C(CH(3))(2)– groups. Within the cavity, there are two ammonium–amine N—H⋯N hydrogen bonds. Supramolecular layers are formed in the crystal packing whereby the water molecule links two perchlorate anions, and the resultant aggregates are connected to the dications via N—H⋯O hydrogen bonds. Layers, with an undulating topology, stack along the a axis being connected by C—H⋯O interactions. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344117/ /pubmed/22606120 http://dx.doi.org/10.1107/S1600536812012135 Text en © Hazari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hazari, Saroj K. S. Roy, Tapashi G. Nath, Babul Chandra Roy, Prashun G. Ng, Seik Weng Tiekink, Edward R. T. 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate |
title | 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate |
title_full | 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate |
title_fullStr | 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate |
title_full_unstemmed | 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate |
title_short | 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate |
title_sort | 5,7,7,12,14,14-hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane bis(perchlorate) monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344117/ https://www.ncbi.nlm.nih.gov/pubmed/22606120 http://dx.doi.org/10.1107/S1600536812012135 |
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