4-[Bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium 2-hy­droxy­benzoate 2-hy­droxy­benzoic acid monosolvate

The title compound, C(17)H(19)F(2)N(2) (+)·C(7)H(5)O(3) (−)·C(7)H(6)O(3), is a co-crystal from 4-[bis­(4-fluoro­phen­yl)meth­yl]piperazin-1-ium, salicylate anion and salicylic acid in a 1:1:1 ratio. In addition to an intra­molecular O—H⋯O hydrogen bond, the crystal packing shows hydrogen bonds betwe...

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Detalles Bibliográficos
Autores principales: Dayananda, A. S., Yathirajan, H. S., Flörke, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344118/
https://www.ncbi.nlm.nih.gov/pubmed/22606121
http://dx.doi.org/10.1107/S1600536812012329
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author Dayananda, A. S.
Yathirajan, H. S.
Flörke, Ulrich
author_facet Dayananda, A. S.
Yathirajan, H. S.
Flörke, Ulrich
author_sort Dayananda, A. S.
collection PubMed
description The title compound, C(17)H(19)F(2)N(2) (+)·C(7)H(5)O(3) (−)·C(7)H(6)O(3), is a co-crystal from 4-[bis­(4-fluoro­phen­yl)meth­yl]piperazin-1-ium, salicylate anion and salicylic acid in a 1:1:1 ratio. In addition to an intra­molecular O—H⋯O hydrogen bond, the crystal packing shows hydrogen bonds between the piperazinium cation and salicylate anion (N—H⋯O), as well as between the salicylic acid mol­ecule and anion (O—H⋯O), giving rise to a three-dimensional network.
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spelling pubmed-33441182012-05-17 4-[Bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium 2-hy­droxy­benzoate 2-hy­droxy­benzoic acid monosolvate Dayananda, A. S. Yathirajan, H. S. Flörke, Ulrich Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(19)F(2)N(2) (+)·C(7)H(5)O(3) (−)·C(7)H(6)O(3), is a co-crystal from 4-[bis­(4-fluoro­phen­yl)meth­yl]piperazin-1-ium, salicylate anion and salicylic acid in a 1:1:1 ratio. In addition to an intra­molecular O—H⋯O hydrogen bond, the crystal packing shows hydrogen bonds between the piperazinium cation and salicylate anion (N—H⋯O), as well as between the salicylic acid mol­ecule and anion (O—H⋯O), giving rise to a three-dimensional network. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3344118/ /pubmed/22606121 http://dx.doi.org/10.1107/S1600536812012329 Text en © Dayananda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dayananda, A. S.
Yathirajan, H. S.
Flörke, Ulrich
4-[Bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium 2-hy­droxy­benzoate 2-hy­droxy­benzoic acid monosolvate
title 4-[Bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium 2-hy­droxy­benzoate 2-hy­droxy­benzoic acid monosolvate
title_full 4-[Bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium 2-hy­droxy­benzoate 2-hy­droxy­benzoic acid monosolvate
title_fullStr 4-[Bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium 2-hy­droxy­benzoate 2-hy­droxy­benzoic acid monosolvate
title_full_unstemmed 4-[Bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium 2-hy­droxy­benzoate 2-hy­droxy­benzoic acid monosolvate
title_short 4-[Bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium 2-hy­droxy­benzoate 2-hy­droxy­benzoic acid monosolvate
title_sort 4-[bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium 2-hy­droxy­benzoate 2-hy­droxy­benzoic acid monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344118/
https://www.ncbi.nlm.nih.gov/pubmed/22606121
http://dx.doi.org/10.1107/S1600536812012329
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AT florkeulrich 4bis4fluorophenylmethylpiperazin1ium2hydroxybenzoate2hydroxybenzoicacidmonosolvate

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