1,1′:4′,1′′-Terphenyl-2′,5′-dicarb­oxy­lic acid dimethyl sulfoxide-d (6) disolvate

The asymmetric unit of the title solvate, C(20)H(14)O(4)·2C(2)D(6)OS, contains half of the substituted terephthalic acid mol­ecule and one solvent mol­ecule. The centroid of the central benzene ring in the acid mol­ecule is coincident with a crystallographic inversion center. Neither the carboxyl no...

Descripción completa

Detalles Bibliográficos
Autores principales: Pop, Lucian C., Preite, Marcelo, Manriquez, Juan Manuel, Vega, Andrés, Chavez, Ivonne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344129/
https://www.ncbi.nlm.nih.gov/pubmed/22606132
http://dx.doi.org/10.1107/S1600536812012056
_version_ 1782231922322178048
author Pop, Lucian C.
Preite, Marcelo
Manriquez, Juan Manuel
Vega, Andrés
Chavez, Ivonne
author_facet Pop, Lucian C.
Preite, Marcelo
Manriquez, Juan Manuel
Vega, Andrés
Chavez, Ivonne
author_sort Pop, Lucian C.
collection PubMed
description The asymmetric unit of the title solvate, C(20)H(14)O(4)·2C(2)D(6)OS, contains half of the substituted terephthalic acid mol­ecule and one solvent mol­ecule. The centroid of the central benzene ring in the acid mol­ecule is coincident with a crystallographic inversion center. Neither the carboxyl nor the phenyl substituents are coplanar with the central aromatic ring, showing dihedral angles of 53.18 (11) and 47.83 (11)°, respectively. The dimethyl sulfoxide solvent mol­ecules are hydrogen bonded to the carb­oxy­lic acid groups.
format Online
Article
Text
id pubmed-3344129
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33441292012-05-17 1,1′:4′,1′′-Terphenyl-2′,5′-dicarb­oxy­lic acid dimethyl sulfoxide-d (6) disolvate Pop, Lucian C. Preite, Marcelo Manriquez, Juan Manuel Vega, Andrés Chavez, Ivonne Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title solvate, C(20)H(14)O(4)·2C(2)D(6)OS, contains half of the substituted terephthalic acid mol­ecule and one solvent mol­ecule. The centroid of the central benzene ring in the acid mol­ecule is coincident with a crystallographic inversion center. Neither the carboxyl nor the phenyl substituents are coplanar with the central aromatic ring, showing dihedral angles of 53.18 (11) and 47.83 (11)°, respectively. The dimethyl sulfoxide solvent mol­ecules are hydrogen bonded to the carb­oxy­lic acid groups. International Union of Crystallography 2012-03-28 /pmc/articles/PMC3344129/ /pubmed/22606132 http://dx.doi.org/10.1107/S1600536812012056 Text en © Pop et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pop, Lucian C.
Preite, Marcelo
Manriquez, Juan Manuel
Vega, Andrés
Chavez, Ivonne
1,1′:4′,1′′-Terphenyl-2′,5′-dicarb­oxy­lic acid dimethyl sulfoxide-d (6) disolvate
title 1,1′:4′,1′′-Terphenyl-2′,5′-dicarb­oxy­lic acid dimethyl sulfoxide-d (6) disolvate
title_full 1,1′:4′,1′′-Terphenyl-2′,5′-dicarb­oxy­lic acid dimethyl sulfoxide-d (6) disolvate
title_fullStr 1,1′:4′,1′′-Terphenyl-2′,5′-dicarb­oxy­lic acid dimethyl sulfoxide-d (6) disolvate
title_full_unstemmed 1,1′:4′,1′′-Terphenyl-2′,5′-dicarb­oxy­lic acid dimethyl sulfoxide-d (6) disolvate
title_short 1,1′:4′,1′′-Terphenyl-2′,5′-dicarb­oxy­lic acid dimethyl sulfoxide-d (6) disolvate
title_sort 1,1′:4′,1′′-terphenyl-2′,5′-dicarb­oxy­lic acid dimethyl sulfoxide-d (6) disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344129/
https://www.ncbi.nlm.nih.gov/pubmed/22606132
http://dx.doi.org/10.1107/S1600536812012056
work_keys_str_mv AT poplucianc 1141terphenyl25dicarboxylicaciddimethylsulfoxided6disolvate
AT preitemarcelo 1141terphenyl25dicarboxylicaciddimethylsulfoxided6disolvate
AT manriquezjuanmanuel 1141terphenyl25dicarboxylicaciddimethylsulfoxided6disolvate
AT vegaandres 1141terphenyl25dicarboxylicaciddimethylsulfoxided6disolvate
AT chavezivonne 1141terphenyl25dicarboxylicaciddimethylsulfoxided6disolvate

Ejemplares similares