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Cyclo­octanaminium hydrogen succinate monohydrate

In the title hydrated salt, C(8)H(18)N(+)·C(4)H(5)O(4) (−)·H(2)O, the cyclo­octyl­ ring of the cation is disordered over two positions in a 0.833 (3):0.167 (3) ratio. The structure contains various O—H.·O and N—H⋯O inter­actions, forming a hydrogen-bonded layer of mol­ecules perpendicular to the c a...

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Detalles Bibliográficos
Autores principales: Khorasani, Sanaz, Fernandes, Manuel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344141/
https://www.ncbi.nlm.nih.gov/pubmed/22606144
http://dx.doi.org/10.1107/S1600536812011208
Descripción
Sumario:In the title hydrated salt, C(8)H(18)N(+)·C(4)H(5)O(4) (−)·H(2)O, the cyclo­octyl­ ring of the cation is disordered over two positions in a 0.833 (3):0.167 (3) ratio. The structure contains various O—H.·O and N—H⋯O inter­actions, forming a hydrogen-bonded layer of mol­ecules perpendicular to the c axis. In each layer, the ammonium cation hydrogen bonds to two hydrogen succinate anions and one water mol­ecule. Each hydrogen succinate anion hydrogen bonds to neighbouring anions, forming a chain of mol­ecules along the b axis. In addition, each hydrogen succinate anion hydrogen bonds to two water mol­ecules and the ammonium cation.