Cyclo­octanaminium hydrogen succinate monohydrate

In the title hydrated salt, C(8)H(18)N(+)·C(4)H(5)O(4) (−)·H(2)O, the cyclo­octyl­ ring of the cation is disordered over two positions in a 0.833 (3):0.167 (3) ratio. The structure contains various O—H.·O and N—H⋯O inter­actions, forming a hydrogen-bonded layer of mol­ecules perpendicular to the c a...

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Detalles Bibliográficos
Autores principales: Khorasani, Sanaz, Fernandes, Manuel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344141/
https://www.ncbi.nlm.nih.gov/pubmed/22606144
http://dx.doi.org/10.1107/S1600536812011208
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author Khorasani, Sanaz
Fernandes, Manuel A.
author_facet Khorasani, Sanaz
Fernandes, Manuel A.
author_sort Khorasani, Sanaz
collection PubMed
description In the title hydrated salt, C(8)H(18)N(+)·C(4)H(5)O(4) (−)·H(2)O, the cyclo­octyl­ ring of the cation is disordered over two positions in a 0.833 (3):0.167 (3) ratio. The structure contains various O—H.·O and N—H⋯O inter­actions, forming a hydrogen-bonded layer of mol­ecules perpendicular to the c axis. In each layer, the ammonium cation hydrogen bonds to two hydrogen succinate anions and one water mol­ecule. Each hydrogen succinate anion hydrogen bonds to neighbouring anions, forming a chain of mol­ecules along the b axis. In addition, each hydrogen succinate anion hydrogen bonds to two water mol­ecules and the ammonium cation.
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spelling pubmed-33441412012-05-17 Cyclo­octanaminium hydrogen succinate monohydrate Khorasani, Sanaz Fernandes, Manuel A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated salt, C(8)H(18)N(+)·C(4)H(5)O(4) (−)·H(2)O, the cyclo­octyl­ ring of the cation is disordered over two positions in a 0.833 (3):0.167 (3) ratio. The structure contains various O—H.·O and N—H⋯O inter­actions, forming a hydrogen-bonded layer of mol­ecules perpendicular to the c axis. In each layer, the ammonium cation hydrogen bonds to two hydrogen succinate anions and one water mol­ecule. Each hydrogen succinate anion hydrogen bonds to neighbouring anions, forming a chain of mol­ecules along the b axis. In addition, each hydrogen succinate anion hydrogen bonds to two water mol­ecules and the ammonium cation. International Union of Crystallography 2012-03-28 /pmc/articles/PMC3344141/ /pubmed/22606144 http://dx.doi.org/10.1107/S1600536812011208 Text en © Khorasani and Fernandes 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khorasani, Sanaz
Fernandes, Manuel A.
Cyclo­octanaminium hydrogen succinate monohydrate
title Cyclo­octanaminium hydrogen succinate monohydrate
title_full Cyclo­octanaminium hydrogen succinate monohydrate
title_fullStr Cyclo­octanaminium hydrogen succinate monohydrate
title_full_unstemmed Cyclo­octanaminium hydrogen succinate monohydrate
title_short Cyclo­octanaminium hydrogen succinate monohydrate
title_sort cyclo­octanaminium hydrogen succinate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344141/
https://www.ncbi.nlm.nih.gov/pubmed/22606144
http://dx.doi.org/10.1107/S1600536812011208
work_keys_str_mv AT khorasanisanaz cyclooctanaminiumhydrogensuccinatemonohydrate
AT fernandesmanuela cyclooctanaminiumhydrogensuccinatemonohydrate

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