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3β-Chloro-5α-cholestan-6-one

The asymmetric unit of the title compound, C(27)H(45)ClO, consists of two crystallographically independent mol­ecules. In both mol­ecules, the three cyclo­hexane rings in the steroid fused-ring systems adopt chair conformations, while the cyclo­pentane ring adopts a half-chair conformation in one mo...

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Detalles Bibliográficos
Autores principales: Yusufzai, Samina Khan, Osman, Hasnah, Rahim, Aisyah Saad Abdul, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344147/
https://www.ncbi.nlm.nih.gov/pubmed/22606150
http://dx.doi.org/10.1107/S1600536812012482
Descripción
Sumario:The asymmetric unit of the title compound, C(27)H(45)ClO, consists of two crystallographically independent mol­ecules. In both mol­ecules, the three cyclo­hexane rings in the steroid fused-ring systems adopt chair conformations, while the cyclo­pentane ring adopts a half-chair conformation in one mol­ecule and an envelope conformation in the other. In the crystal, the mol­ecules are linked into a two-dimensional network by weak C—H⋯O hydrogen bonds. The crystal studied is a nonmerohedral twin with a refined ratio of twin components of 0.264 (3):0.736 (3).