7-Chloro-4-[(E)-2-(3,4,5-trimeth­oxy­benzyl­idene)hydrazin-1-yl]quinoline

In the title compound, C(19)H(18)ClN(3)O(3), the r.m.s. deviation through the 23 non-H and non-meth­oxy atoms is 0.088 Å, indicating a planar mol­ecule with the exception of the meth­oxy groups. One meth­oxy group, surrounded on either side by the other meth­oxy groups, is almost normal to the benze...

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Detalles Bibliográficos
Autores principales: Ferreira, Marcelle de Lima, de Souza, Marcus V. N., Wardell, Solange M. S. V., Tiekink, Edward R. T., Wardell, James L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344149/
https://www.ncbi.nlm.nih.gov/pubmed/22606152
http://dx.doi.org/10.1107/S1600536812012755
Descripción
Sumario:In the title compound, C(19)H(18)ClN(3)O(3), the r.m.s. deviation through the 23 non-H and non-meth­oxy atoms is 0.088 Å, indicating a planar mol­ecule with the exception of the meth­oxy groups. One meth­oxy group, surrounded on either side by the other meth­oxy groups, is almost normal to the benzene ring to which it is connected [C—O—C(ar)—C(ar) torsion angle = 81.64 (15)°]. In the crystal, N—H⋯O, C—H⋯O and π–π inter­actions [between quinoline residues; centroid–centroid distance = 3.4375 (8) Å] link mol­ecules into a three-dimensional architecture.

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