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7-Chloro-4-[(E)-2-(3,4,5-trimethoxybenzylidene)hydrazin-1-yl]quinoline
In the title compound, C(19)H(18)ClN(3)O(3), the r.m.s. deviation through the 23 non-H and non-methoxy atoms is 0.088 Å, indicating a planar molecule with the exception of the methoxy groups. One methoxy group, surrounded on either side by the other methoxy groups, is almost normal to the benze...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344149/ https://www.ncbi.nlm.nih.gov/pubmed/22606152 http://dx.doi.org/10.1107/S1600536812012755 |
| _version_ | 1782231926821617664 |
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| author | Ferreira, Marcelle de Lima de Souza, Marcus V. N. Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. |
| author_facet | Ferreira, Marcelle de Lima de Souza, Marcus V. N. Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. |
| author_sort | Ferreira, Marcelle de Lima |
| collection | PubMed |
| description | In the title compound, C(19)H(18)ClN(3)O(3), the r.m.s. deviation through the 23 non-H and non-methoxy atoms is 0.088 Å, indicating a planar molecule with the exception of the methoxy groups. One methoxy group, surrounded on either side by the other methoxy groups, is almost normal to the benzene ring to which it is connected [C—O—C(ar)—C(ar) torsion angle = 81.64 (15)°]. In the crystal, N—H⋯O, C—H⋯O and π–π interactions [between quinoline residues; centroid–centroid distance = 3.4375 (8) Å] link molecules into a three-dimensional architecture. |
| format | Online Article Text |
| id | pubmed-3344149 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33441492012-05-17 7-Chloro-4-[(E)-2-(3,4,5-trimethoxybenzylidene)hydrazin-1-yl]quinoline Ferreira, Marcelle de Lima de Souza, Marcus V. N. Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(18)ClN(3)O(3), the r.m.s. deviation through the 23 non-H and non-methoxy atoms is 0.088 Å, indicating a planar molecule with the exception of the methoxy groups. One methoxy group, surrounded on either side by the other methoxy groups, is almost normal to the benzene ring to which it is connected [C—O—C(ar)—C(ar) torsion angle = 81.64 (15)°]. In the crystal, N—H⋯O, C—H⋯O and π–π interactions [between quinoline residues; centroid–centroid distance = 3.4375 (8) Å] link molecules into a three-dimensional architecture. International Union of Crystallography 2012-03-28 /pmc/articles/PMC3344149/ /pubmed/22606152 http://dx.doi.org/10.1107/S1600536812012755 Text en © Ferreira et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Ferreira, Marcelle de Lima de Souza, Marcus V. N. Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. 7-Chloro-4-[(E)-2-(3,4,5-trimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title | 7-Chloro-4-[(E)-2-(3,4,5-trimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_full | 7-Chloro-4-[(E)-2-(3,4,5-trimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_fullStr | 7-Chloro-4-[(E)-2-(3,4,5-trimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_full_unstemmed | 7-Chloro-4-[(E)-2-(3,4,5-trimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_short | 7-Chloro-4-[(E)-2-(3,4,5-trimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_sort | 7-chloro-4-[(e)-2-(3,4,5-trimethoxybenzylidene)hydrazin-1-yl]quinoline |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344149/ https://www.ncbi.nlm.nih.gov/pubmed/22606152 http://dx.doi.org/10.1107/S1600536812012755 |
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