Benzyl 2-methyl-3-[(E)-(thio­phen-2-yl)methyl­idene]dithio­carbazate

In the title compound, C(14)H(14)N(2)S(3), the thione S atom and methyl group are syn, as are the two thio­ether S atoms. The mol­ecule is twisted, the dihedral angles between the central (C(2)N(2)S(2)) residue and the pendent 2-thienyl and phenyl rings being 21.57 (6) and 77.54 (3)°, respectively....

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Detalles Bibliográficos
Autores principales: Hazari, Saroj K. S., Dey, B. K., Roy, Tapashi G., Ganguly, B., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344150/
https://www.ncbi.nlm.nih.gov/pubmed/22606153
http://dx.doi.org/10.1107/S1600536812012652
Descripción
Sumario:In the title compound, C(14)H(14)N(2)S(3), the thione S atom and methyl group are syn, as are the two thio­ether S atoms. The mol­ecule is twisted, the dihedral angles between the central (C(2)N(2)S(2)) residue and the pendent 2-thienyl and phenyl rings being 21.57 (6) and 77.54 (3)°, respectively. In the crystal, mol­ecules assemble into a three-dimensional architecture via C—H⋯π inter­actions, involving both the five- and six-membered rings as acceptors, as well as S⋯S inter­actions [3.3406 (5) Å] between centrosymmetrically related 2-thienyl rings.

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