Benzyl 2-methyl-3-[(E)-(thio­phen-2-yl)methyl­idene]dithio­carbazate

In the title compound, C(14)H(14)N(2)S(3), the thione S atom and methyl group are syn, as are the two thio­ether S atoms. The mol­ecule is twisted, the dihedral angles between the central (C(2)N(2)S(2)) residue and the pendent 2-thienyl and phenyl rings being 21.57 (6) and 77.54 (3)°, respectively....

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Detalles Bibliográficos
Autores principales: Hazari, Saroj K. S., Dey, B. K., Roy, Tapashi G., Ganguly, B., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344150/
https://www.ncbi.nlm.nih.gov/pubmed/22606153
http://dx.doi.org/10.1107/S1600536812012652
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author Hazari, Saroj K. S.
Dey, B. K.
Roy, Tapashi G.
Ganguly, B.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Hazari, Saroj K. S.
Dey, B. K.
Roy, Tapashi G.
Ganguly, B.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Hazari, Saroj K. S.
collection PubMed
description In the title compound, C(14)H(14)N(2)S(3), the thione S atom and methyl group are syn, as are the two thio­ether S atoms. The mol­ecule is twisted, the dihedral angles between the central (C(2)N(2)S(2)) residue and the pendent 2-thienyl and phenyl rings being 21.57 (6) and 77.54 (3)°, respectively. In the crystal, mol­ecules assemble into a three-dimensional architecture via C—H⋯π inter­actions, involving both the five- and six-membered rings as acceptors, as well as S⋯S inter­actions [3.3406 (5) Å] between centrosymmetrically related 2-thienyl rings.
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spelling pubmed-33441502012-05-17 Benzyl 2-methyl-3-[(E)-(thio­phen-2-yl)methyl­idene]dithio­carbazate Hazari, Saroj K. S. Dey, B. K. Roy, Tapashi G. Ganguly, B. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)N(2)S(3), the thione S atom and methyl group are syn, as are the two thio­ether S atoms. The mol­ecule is twisted, the dihedral angles between the central (C(2)N(2)S(2)) residue and the pendent 2-thienyl and phenyl rings being 21.57 (6) and 77.54 (3)°, respectively. In the crystal, mol­ecules assemble into a three-dimensional architecture via C—H⋯π inter­actions, involving both the five- and six-membered rings as acceptors, as well as S⋯S inter­actions [3.3406 (5) Å] between centrosymmetrically related 2-thienyl rings. International Union of Crystallography 2012-03-28 /pmc/articles/PMC3344150/ /pubmed/22606153 http://dx.doi.org/10.1107/S1600536812012652 Text en © Hazari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hazari, Saroj K. S.
Dey, B. K.
Roy, Tapashi G.
Ganguly, B.
Ng, Seik Weng
Tiekink, Edward R. T.
Benzyl 2-methyl-3-[(E)-(thio­phen-2-yl)methyl­idene]dithio­carbazate
title Benzyl 2-methyl-3-[(E)-(thio­phen-2-yl)methyl­idene]dithio­carbazate
title_full Benzyl 2-methyl-3-[(E)-(thio­phen-2-yl)methyl­idene]dithio­carbazate
title_fullStr Benzyl 2-methyl-3-[(E)-(thio­phen-2-yl)methyl­idene]dithio­carbazate
title_full_unstemmed Benzyl 2-methyl-3-[(E)-(thio­phen-2-yl)methyl­idene]dithio­carbazate
title_short Benzyl 2-methyl-3-[(E)-(thio­phen-2-yl)methyl­idene]dithio­carbazate
title_sort benzyl 2-methyl-3-[(e)-(thio­phen-2-yl)methyl­idene]dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344150/
https://www.ncbi.nlm.nih.gov/pubmed/22606153
http://dx.doi.org/10.1107/S1600536812012652
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