4-Nitro-2-{[(tricyclo­[3.3.1.1(3,7)]decan-1-yl)iminium­yl]meth­yl}phenolate

The title compound, C(17)H(20)N(2)O(3), is a Schiff base, which is found as a zwitterion in the solid state. The geometry around the iminium N atom indicates sp (2)-hybridization. The zwitterion shows a strong intra­molecular N—H⋯O hydrogen-bond inter­action between the iminium N atom and the phenol...

Descripción completa

Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344155/
https://www.ncbi.nlm.nih.gov/pubmed/22606158
http://dx.doi.org/10.1107/S1600536812012597
_version_ 1782231928149114880
author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The title compound, C(17)H(20)N(2)O(3), is a Schiff base, which is found as a zwitterion in the solid state. The geometry around the iminium N atom indicates sp (2)-hybridization. The zwitterion shows a strong intra­molecular N—H⋯O hydrogen-bond inter­action between the iminium N atom and the phenolate O atom.
format Online
Article
Text
id pubmed-3344155
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33441552012-05-17 4-Nitro-2-{[(tricyclo­[3.3.1.1(3,7)]decan-1-yl)iminium­yl]meth­yl}phenolate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(20)N(2)O(3), is a Schiff base, which is found as a zwitterion in the solid state. The geometry around the iminium N atom indicates sp (2)-hybridization. The zwitterion shows a strong intra­molecular N—H⋯O hydrogen-bond inter­action between the iminium N atom and the phenolate O atom. International Union of Crystallography 2012-03-28 /pmc/articles/PMC3344155/ /pubmed/22606158 http://dx.doi.org/10.1107/S1600536812012597 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ha, Kwang
4-Nitro-2-{[(tricyclo­[3.3.1.1(3,7)]decan-1-yl)iminium­yl]meth­yl}phenolate
title 4-Nitro-2-{[(tricyclo­[3.3.1.1(3,7)]decan-1-yl)iminium­yl]meth­yl}phenolate
title_full 4-Nitro-2-{[(tricyclo­[3.3.1.1(3,7)]decan-1-yl)iminium­yl]meth­yl}phenolate
title_fullStr 4-Nitro-2-{[(tricyclo­[3.3.1.1(3,7)]decan-1-yl)iminium­yl]meth­yl}phenolate
title_full_unstemmed 4-Nitro-2-{[(tricyclo­[3.3.1.1(3,7)]decan-1-yl)iminium­yl]meth­yl}phenolate
title_short 4-Nitro-2-{[(tricyclo­[3.3.1.1(3,7)]decan-1-yl)iminium­yl]meth­yl}phenolate
title_sort 4-nitro-2-{[(tricyclo­[3.3.1.1(3,7)]decan-1-yl)iminium­yl]meth­yl}phenolate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344155/
https://www.ncbi.nlm.nih.gov/pubmed/22606158
http://dx.doi.org/10.1107/S1600536812012597
work_keys_str_mv AT hakwang 4nitro2tricyclo331137decan1yliminiumylmethylphenolate

Ejemplares similares