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1,4-Phenyl­enebis(methyl­ene) dicarbamate

The title compound, C(10)H(12)N(2)O(4), is a phenyl dicarbamate with crystallographically imposed inversion symmetry. The dihedral angle between the carbamo­yloxy plane [i.e. the plane of the N—C(O)—O fragment; r.m.s. deviation = 0.002 (3) Å] and the plane of the aryl ring is 29.2 (1)°. In the cryst...

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Detalles Bibliográficos
Autor principal: Li, Zhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344159/
https://www.ncbi.nlm.nih.gov/pubmed/22606162
http://dx.doi.org/10.1107/S1600536812012718
Descripción
Sumario:The title compound, C(10)H(12)N(2)O(4), is a phenyl dicarbamate with crystallographically imposed inversion symmetry. The dihedral angle between the carbamo­yloxy plane [i.e. the plane of the N—C(O)—O fragment; r.m.s. deviation = 0.002 (3) Å] and the plane of the aryl ring is 29.2 (1)°. In the crystal, two different centrosymmetric N—H⋯O hydrogen-bond inter­actions are observed; these are described as R (2) (2)(8) and R (2) (4)(8) in graph-set notation. The rings form an alternating sequence, linking the mol­ecules into a sheet structure parallel to (011).