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1,4-Phenylenebis(methylene) dicarbamate
The title compound, C(10)H(12)N(2)O(4), is a phenyl dicarbamate with crystallographically imposed inversion symmetry. The dihedral angle between the carbamoyloxy plane [i.e. the plane of the N—C(O)—O fragment; r.m.s. deviation = 0.002 (3) Å] and the plane of the aryl ring is 29.2 (1)°. In the cryst...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344159/ https://www.ncbi.nlm.nih.gov/pubmed/22606162 http://dx.doi.org/10.1107/S1600536812012718 |
Sumario: | The title compound, C(10)H(12)N(2)O(4), is a phenyl dicarbamate with crystallographically imposed inversion symmetry. The dihedral angle between the carbamoyloxy plane [i.e. the plane of the N—C(O)—O fragment; r.m.s. deviation = 0.002 (3) Å] and the plane of the aryl ring is 29.2 (1)°. In the crystal, two different centrosymmetric N—H⋯O hydrogen-bond interactions are observed; these are described as R (2) (2)(8) and R (2) (4)(8) in graph-set notation. The rings form an alternating sequence, linking the molecules into a sheet structure parallel to (011). |
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