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1,4-Phenyl­enebis(methyl­ene) dicarbamate

The title compound, C(10)H(12)N(2)O(4), is a phenyl dicarbamate with crystallographically imposed inversion symmetry. The dihedral angle between the carbamo­yloxy plane [i.e. the plane of the N—C(O)—O fragment; r.m.s. deviation = 0.002 (3) Å] and the plane of the aryl ring is 29.2 (1)°. In the cryst...

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Detalles Bibliográficos
Autor principal: Li, Zhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344159/
https://www.ncbi.nlm.nih.gov/pubmed/22606162
http://dx.doi.org/10.1107/S1600536812012718
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author Li, Zhi
author_facet Li, Zhi
author_sort Li, Zhi
collection PubMed
description The title compound, C(10)H(12)N(2)O(4), is a phenyl dicarbamate with crystallographically imposed inversion symmetry. The dihedral angle between the carbamo­yloxy plane [i.e. the plane of the N—C(O)—O fragment; r.m.s. deviation = 0.002 (3) Å] and the plane of the aryl ring is 29.2 (1)°. In the crystal, two different centrosymmetric N—H⋯O hydrogen-bond inter­actions are observed; these are described as R (2) (2)(8) and R (2) (4)(8) in graph-set notation. The rings form an alternating sequence, linking the mol­ecules into a sheet structure parallel to (011).
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spelling pubmed-33441592012-05-17 1,4-Phenyl­enebis(methyl­ene) dicarbamate Li, Zhi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)N(2)O(4), is a phenyl dicarbamate with crystallographically imposed inversion symmetry. The dihedral angle between the carbamo­yloxy plane [i.e. the plane of the N—C(O)—O fragment; r.m.s. deviation = 0.002 (3) Å] and the plane of the aryl ring is 29.2 (1)°. In the crystal, two different centrosymmetric N—H⋯O hydrogen-bond inter­actions are observed; these are described as R (2) (2)(8) and R (2) (4)(8) in graph-set notation. The rings form an alternating sequence, linking the mol­ecules into a sheet structure parallel to (011). International Union of Crystallography 2012-03-31 /pmc/articles/PMC3344159/ /pubmed/22606162 http://dx.doi.org/10.1107/S1600536812012718 Text en © Zhi Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Zhi
1,4-Phenyl­enebis(methyl­ene) dicarbamate
title 1,4-Phenyl­enebis(methyl­ene) dicarbamate
title_full 1,4-Phenyl­enebis(methyl­ene) dicarbamate
title_fullStr 1,4-Phenyl­enebis(methyl­ene) dicarbamate
title_full_unstemmed 1,4-Phenyl­enebis(methyl­ene) dicarbamate
title_short 1,4-Phenyl­enebis(methyl­ene) dicarbamate
title_sort 1,4-phenyl­enebis(methyl­ene) dicarbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344159/
https://www.ncbi.nlm.nih.gov/pubmed/22606162
http://dx.doi.org/10.1107/S1600536812012718
work_keys_str_mv AT lizhi 14phenylenebismethylenedicarbamate