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4-[(E)-2-(2,4-Dichlorobenzylidene)hydrazin-1-yl]quinolin-1-ium chloride monohydrate
In the title hydrated salt, C(16)H(12)Cl(2)N(3) (+)·Cl(−)·H(2)O, there is a small twist in the cation as seen in the torsion angle linking the benzene ring to the rest of the molecule [171.96 (17)°]. In the crystal, the quinolinium H atom forms a hydrogen bond to the lattice water molecule, which...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344163/ https://www.ncbi.nlm.nih.gov/pubmed/22606166 http://dx.doi.org/10.1107/S1600536812012962 |
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| author | Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. Ferreira, Marcelle de Lima de Souza, Marcus V. N. |
| author_facet | Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. Ferreira, Marcelle de Lima de Souza, Marcus V. N. |
| author_sort | Wardell, Solange M. S. V. |
| collection | PubMed |
| description | In the title hydrated salt, C(16)H(12)Cl(2)N(3) (+)·Cl(−)·H(2)O, there is a small twist in the cation as seen in the torsion angle linking the benzene ring to the rest of the molecule [171.96 (17)°]. In the crystal, the quinolinium H atom forms a hydrogen bond to the lattice water molecule, which also forms hydrogen bonds to two Cl(−) anions. Each Cl(−) ion also accepts a hydrogen bond from the hydrazine H atom. The three-dimensional architecture is also stabilized by π–π interactions between centrosymmetrically related quinoline residues [centroid–centroid distance = 3.5574 (11) Å]. |
| format | Online Article Text |
| id | pubmed-3344163 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33441632012-05-17 4-[(E)-2-(2,4-Dichlorobenzylidene)hydrazin-1-yl]quinolin-1-ium chloride monohydrate Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. Ferreira, Marcelle de Lima de Souza, Marcus V. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated salt, C(16)H(12)Cl(2)N(3) (+)·Cl(−)·H(2)O, there is a small twist in the cation as seen in the torsion angle linking the benzene ring to the rest of the molecule [171.96 (17)°]. In the crystal, the quinolinium H atom forms a hydrogen bond to the lattice water molecule, which also forms hydrogen bonds to two Cl(−) anions. Each Cl(−) ion also accepts a hydrogen bond from the hydrazine H atom. The three-dimensional architecture is also stabilized by π–π interactions between centrosymmetrically related quinoline residues [centroid–centroid distance = 3.5574 (11) Å]. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3344163/ /pubmed/22606166 http://dx.doi.org/10.1107/S1600536812012962 Text en © Wardell et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. Ferreira, Marcelle de Lima de Souza, Marcus V. N. 4-[(E)-2-(2,4-Dichlorobenzylidene)hydrazin-1-yl]quinolin-1-ium chloride monohydrate |
| title | 4-[(E)-2-(2,4-Dichlorobenzylidene)hydrazin-1-yl]quinolin-1-ium chloride monohydrate |
| title_full | 4-[(E)-2-(2,4-Dichlorobenzylidene)hydrazin-1-yl]quinolin-1-ium chloride monohydrate |
| title_fullStr | 4-[(E)-2-(2,4-Dichlorobenzylidene)hydrazin-1-yl]quinolin-1-ium chloride monohydrate |
| title_full_unstemmed | 4-[(E)-2-(2,4-Dichlorobenzylidene)hydrazin-1-yl]quinolin-1-ium chloride monohydrate |
| title_short | 4-[(E)-2-(2,4-Dichlorobenzylidene)hydrazin-1-yl]quinolin-1-ium chloride monohydrate |
| title_sort | 4-[(e)-2-(2,4-dichlorobenzylidene)hydrazin-1-yl]quinolin-1-ium chloride monohydrate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344163/ https://www.ncbi.nlm.nih.gov/pubmed/22606166 http://dx.doi.org/10.1107/S1600536812012962 |
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