4-Bromo-N-(4-meth­oxy-2-nitro­phen­yl)benzamide

In the title compound, C(14)H(11)BrN(2)O(4), the amide segment makes dihedral angles of 23.4 (2) and 20.5 (2)° with the benzene rings, while the dihedral angle between the bezene rings is 2.90 (8)°. The nitro and meth­oxy groups are almost coplanar with their bound benzene ring, with the r.m.s. devi...

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Detalles Bibliográficos
Autores principales: Sripet, Weerawat, Chantrapromma, Suchada, Ruanwas, Pumsak, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344164/
https://www.ncbi.nlm.nih.gov/pubmed/22606167
http://dx.doi.org/10.1107/S1600536812010963
Descripción
Sumario:In the title compound, C(14)H(11)BrN(2)O(4), the amide segment makes dihedral angles of 23.4 (2) and 20.5 (2)° with the benzene rings, while the dihedral angle between the bezene rings is 2.90 (8)°. The nitro and meth­oxy groups are almost coplanar with their bound benzene ring, with the r.m.s. deviation for the 11 non-H atoms being 0.0265 (1) Å. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked into [2-10] chains by weak C—H⋯O and C—H⋯Br inter­actions, which form an R (2) (2)(8) motif between pairs of mol­ecules in the chain. A Br⋯O [3.2018 (12) Å] short contact also occurs.

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