4-Bromo-N-(4-meth­oxy-2-nitro­phen­yl)benzamide

In the title compound, C(14)H(11)BrN(2)O(4), the amide segment makes dihedral angles of 23.4 (2) and 20.5 (2)° with the benzene rings, while the dihedral angle between the bezene rings is 2.90 (8)°. The nitro and meth­oxy groups are almost coplanar with their bound benzene ring, with the r.m.s. devi...

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Autores principales: Sripet, Weerawat, Chantrapromma, Suchada, Ruanwas, Pumsak, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344164/
https://www.ncbi.nlm.nih.gov/pubmed/22606167
http://dx.doi.org/10.1107/S1600536812010963
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author Sripet, Weerawat
Chantrapromma, Suchada
Ruanwas, Pumsak
Fun, Hoong-Kun
author_facet Sripet, Weerawat
Chantrapromma, Suchada
Ruanwas, Pumsak
Fun, Hoong-Kun
author_sort Sripet, Weerawat
collection PubMed
description In the title compound, C(14)H(11)BrN(2)O(4), the amide segment makes dihedral angles of 23.4 (2) and 20.5 (2)° with the benzene rings, while the dihedral angle between the bezene rings is 2.90 (8)°. The nitro and meth­oxy groups are almost coplanar with their bound benzene ring, with the r.m.s. deviation for the 11 non-H atoms being 0.0265 (1) Å. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked into [2-10] chains by weak C—H⋯O and C—H⋯Br inter­actions, which form an R (2) (2)(8) motif between pairs of mol­ecules in the chain. A Br⋯O [3.2018 (12) Å] short contact also occurs.
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spelling pubmed-33441642012-05-17 4-Bromo-N-(4-meth­oxy-2-nitro­phen­yl)benzamide Sripet, Weerawat Chantrapromma, Suchada Ruanwas, Pumsak Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(11)BrN(2)O(4), the amide segment makes dihedral angles of 23.4 (2) and 20.5 (2)° with the benzene rings, while the dihedral angle between the bezene rings is 2.90 (8)°. The nitro and meth­oxy groups are almost coplanar with their bound benzene ring, with the r.m.s. deviation for the 11 non-H atoms being 0.0265 (1) Å. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked into [2-10] chains by weak C—H⋯O and C—H⋯Br inter­actions, which form an R (2) (2)(8) motif between pairs of mol­ecules in the chain. A Br⋯O [3.2018 (12) Å] short contact also occurs. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3344164/ /pubmed/22606167 http://dx.doi.org/10.1107/S1600536812010963 Text en © Sripet et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sripet, Weerawat
Chantrapromma, Suchada
Ruanwas, Pumsak
Fun, Hoong-Kun
4-Bromo-N-(4-meth­oxy-2-nitro­phen­yl)benzamide
title 4-Bromo-N-(4-meth­oxy-2-nitro­phen­yl)benzamide
title_full 4-Bromo-N-(4-meth­oxy-2-nitro­phen­yl)benzamide
title_fullStr 4-Bromo-N-(4-meth­oxy-2-nitro­phen­yl)benzamide
title_full_unstemmed 4-Bromo-N-(4-meth­oxy-2-nitro­phen­yl)benzamide
title_short 4-Bromo-N-(4-meth­oxy-2-nitro­phen­yl)benzamide
title_sort 4-bromo-n-(4-meth­oxy-2-nitro­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344164/
https://www.ncbi.nlm.nih.gov/pubmed/22606167
http://dx.doi.org/10.1107/S1600536812010963
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AT chantraprommasuchada 4bromon4methoxy2nitrophenylbenzamide
AT ruanwaspumsak 4bromon4methoxy2nitrophenylbenzamide
AT funhoongkun 4bromon4methoxy2nitrophenylbenzamide

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