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7-Chloro-4-[(E)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline
In the nearly planar title compound (r.m.s. deviation for the 24 non-H atoms = 0.064 Å), C(18)H(16)ClN(3)O(2), the conformation about the N=C bond is E. Supramolecular chains propagated by glide symmetry along [001] are found in the crystal packing. These are sustained by N—H⋯N hydrogen bonds with...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344174/ https://www.ncbi.nlm.nih.gov/pubmed/22606177 http://dx.doi.org/10.1107/S1600536812012871 |
| _version_ | 1782231932402139136 |
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| author | de Souza, Marcus V. N. Ferreira, Marcelle de Lima Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. |
| author_facet | de Souza, Marcus V. N. Ferreira, Marcelle de Lima Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. |
| author_sort | de Souza, Marcus V. N. |
| collection | PubMed |
| description | In the nearly planar title compound (r.m.s. deviation for the 24 non-H atoms = 0.064 Å), C(18)H(16)ClN(3)O(2), the conformation about the N=C bond is E. Supramolecular chains propagated by glide symmetry along [001] are found in the crystal packing. These are sustained by N—H⋯N hydrogen bonds with the quinoline N atom being the acceptor. The chains are connected into a three-dimensional architecture by π–π interactions involving all three aromatic rings [centroid–centroid distances = 3.5650 (9)–3.6264 (9) Å]. |
| format | Online Article Text |
| id | pubmed-3344174 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33441742012-05-17 7-Chloro-4-[(E)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline de Souza, Marcus V. N. Ferreira, Marcelle de Lima Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the nearly planar title compound (r.m.s. deviation for the 24 non-H atoms = 0.064 Å), C(18)H(16)ClN(3)O(2), the conformation about the N=C bond is E. Supramolecular chains propagated by glide symmetry along [001] are found in the crystal packing. These are sustained by N—H⋯N hydrogen bonds with the quinoline N atom being the acceptor. The chains are connected into a three-dimensional architecture by π–π interactions involving all three aromatic rings [centroid–centroid distances = 3.5650 (9)–3.6264 (9) Å]. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3344174/ /pubmed/22606177 http://dx.doi.org/10.1107/S1600536812012871 Text en © Souza et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers de Souza, Marcus V. N. Ferreira, Marcelle de Lima Wardell, Solange M. S. V. Tiekink, Edward R. T. Wardell, James L. 7-Chloro-4-[(E)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title | 7-Chloro-4-[(E)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_full | 7-Chloro-4-[(E)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_fullStr | 7-Chloro-4-[(E)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_full_unstemmed | 7-Chloro-4-[(E)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_short | 7-Chloro-4-[(E)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline |
| title_sort | 7-chloro-4-[(e)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344174/ https://www.ncbi.nlm.nih.gov/pubmed/22606177 http://dx.doi.org/10.1107/S1600536812012871 |
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