(2S,4S)-2-[(S,E)-2-Bromo-1-nitro­methyl-3-phenyl­all­yl]-4-methyl­cyclo­hexa­none

The crystal structure of the title compoud, C(17)H(20)BrNO(3), contains three chiral centers, which all exhibit an S configuration. The C=C double bond has an E conformation. The cyclo­hexane ring is in a chair conformation. In the crystal, mol­ecules are linked by weak N—O⋯Br inter­actions [O⋯Br =...

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Detalles Bibliográficos
Autores principales: Zhao, Long, Wu, Chao, Weng, Wen-Zeng, Yan, Chu-Xia, Xia, Ai-Bao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344181/
https://www.ncbi.nlm.nih.gov/pubmed/22606184
http://dx.doi.org/10.1107/S1600536812013098
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author Zhao, Long
Wu, Chao
Weng, Wen-Zeng
Yan, Chu-Xia
Xia, Ai-Bao
author_facet Zhao, Long
Wu, Chao
Weng, Wen-Zeng
Yan, Chu-Xia
Xia, Ai-Bao
author_sort Zhao, Long
collection PubMed
description The crystal structure of the title compoud, C(17)H(20)BrNO(3), contains three chiral centers, which all exhibit an S configuration. The C=C double bond has an E conformation. The cyclo­hexane ring is in a chair conformation. In the crystal, mol­ecules are linked by weak N—O⋯Br inter­actions [O⋯Br = 3.136 (4) Å].
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spelling pubmed-33441812012-05-17 (2S,4S)-2-[(S,E)-2-Bromo-1-nitro­methyl-3-phenyl­all­yl]-4-methyl­cyclo­hexa­none Zhao, Long Wu, Chao Weng, Wen-Zeng Yan, Chu-Xia Xia, Ai-Bao Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compoud, C(17)H(20)BrNO(3), contains three chiral centers, which all exhibit an S configuration. The C=C double bond has an E conformation. The cyclo­hexane ring is in a chair conformation. In the crystal, mol­ecules are linked by weak N—O⋯Br inter­actions [O⋯Br = 3.136 (4) Å]. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3344181/ /pubmed/22606184 http://dx.doi.org/10.1107/S1600536812013098 Text en © Zhao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Long
Wu, Chao
Weng, Wen-Zeng
Yan, Chu-Xia
Xia, Ai-Bao
(2S,4S)-2-[(S,E)-2-Bromo-1-nitro­methyl-3-phenyl­all­yl]-4-methyl­cyclo­hexa­none
title (2S,4S)-2-[(S,E)-2-Bromo-1-nitro­methyl-3-phenyl­all­yl]-4-methyl­cyclo­hexa­none
title_full (2S,4S)-2-[(S,E)-2-Bromo-1-nitro­methyl-3-phenyl­all­yl]-4-methyl­cyclo­hexa­none
title_fullStr (2S,4S)-2-[(S,E)-2-Bromo-1-nitro­methyl-3-phenyl­all­yl]-4-methyl­cyclo­hexa­none
title_full_unstemmed (2S,4S)-2-[(S,E)-2-Bromo-1-nitro­methyl-3-phenyl­all­yl]-4-methyl­cyclo­hexa­none
title_short (2S,4S)-2-[(S,E)-2-Bromo-1-nitro­methyl-3-phenyl­all­yl]-4-methyl­cyclo­hexa­none
title_sort (2s,4s)-2-[(s,e)-2-bromo-1-nitro­methyl-3-phenyl­all­yl]-4-methyl­cyclo­hexa­none
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344181/
https://www.ncbi.nlm.nih.gov/pubmed/22606184
http://dx.doi.org/10.1107/S1600536812013098
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