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3-Methyl-1-benzofuran-2-carbohydrazide

In the asymmetric unit of the title benzofuran derivative, C(10)H(10)N(2)O(2), there are three crystallograpically independent mol­ecules, which are slightly twisted; the dihedral angle between the benzofuran ring system and the plane of the carbohydrazide unit is 8.64 (11)° in one mol­ecule, wherea...

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Autores principales: Abdel-Aziz, Hatem A., Ghabbour, Hazem A., Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344183/
https://www.ncbi.nlm.nih.gov/pubmed/22606186
http://dx.doi.org/10.1107/S1600536812013190
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author Abdel-Aziz, Hatem A.
Ghabbour, Hazem A.
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Abdel-Aziz, Hatem A.
Ghabbour, Hazem A.
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Abdel-Aziz, Hatem A.
collection PubMed
description In the asymmetric unit of the title benzofuran derivative, C(10)H(10)N(2)O(2), there are three crystallograpically independent mol­ecules, which are slightly twisted; the dihedral angle between the benzofuran ring system and the plane of the carbohydrazide unit is 8.64 (11)° in one mol­ecule, whereas the dihedral angles are 9.58 (11) and 6.89 (10)° in the other two mol­ecules. In the crystal, the three independent mol­ecules are linked to each other through N—H⋯N hydrogen bonds, forming a trimer. The trimers are further linked by weak N—H⋯O and C—H⋯O hydrogen bonds into a three-dimensional network. π–π inter­actions with centroid–centroid distances in the range 3.4928 (11)–3.8561 (10) Å are also observed.
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spelling pubmed-33441832012-05-17 3-Methyl-1-benzofuran-2-carbohydrazide Abdel-Aziz, Hatem A. Ghabbour, Hazem A. Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title benzofuran derivative, C(10)H(10)N(2)O(2), there are three crystallograpically independent mol­ecules, which are slightly twisted; the dihedral angle between the benzofuran ring system and the plane of the carbohydrazide unit is 8.64 (11)° in one mol­ecule, whereas the dihedral angles are 9.58 (11) and 6.89 (10)° in the other two mol­ecules. In the crystal, the three independent mol­ecules are linked to each other through N—H⋯N hydrogen bonds, forming a trimer. The trimers are further linked by weak N—H⋯O and C—H⋯O hydrogen bonds into a three-dimensional network. π–π inter­actions with centroid–centroid distances in the range 3.4928 (11)–3.8561 (10) Å are also observed. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3344183/ /pubmed/22606186 http://dx.doi.org/10.1107/S1600536812013190 Text en © Abdel-Aziz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdel-Aziz, Hatem A.
Ghabbour, Hazem A.
Chantrapromma, Suchada
Fun, Hoong-Kun
3-Methyl-1-benzofuran-2-carbohydrazide
title 3-Methyl-1-benzofuran-2-carbohydrazide
title_full 3-Methyl-1-benzofuran-2-carbohydrazide
title_fullStr 3-Methyl-1-benzofuran-2-carbohydrazide
title_full_unstemmed 3-Methyl-1-benzofuran-2-carbohydrazide
title_short 3-Methyl-1-benzofuran-2-carbohydrazide
title_sort 3-methyl-1-benzofuran-2-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344183/
https://www.ncbi.nlm.nih.gov/pubmed/22606186
http://dx.doi.org/10.1107/S1600536812013190
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