2-Vinyl­pyridine–tris­(penta­fluoro­phen­yl)borane hexane monosolvate

The title compound, C(7)H(7)N·B(C(6)F(5))(3)·C(6)H(14), was obtained by the stoichiometric reaction of 2-vinyl­pyridine and tris­(penta­fluoro­phen­yl)borane in toluene. The formed adduct exhibits a restricted rotation along the B—N bond resulting in an asymmetry, which can be also observed in the (...

Descripción completa

Detalles Bibliográficos
Autores principales: Klahn, Marcus, Spannenberg, Anke, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344187/
https://www.ncbi.nlm.nih.gov/pubmed/22606190
http://dx.doi.org/10.1107/S1600536812013153
_version_ 1782231935348637696
author Klahn, Marcus
Spannenberg, Anke
Rosenthal, Uwe
author_facet Klahn, Marcus
Spannenberg, Anke
Rosenthal, Uwe
author_sort Klahn, Marcus
collection PubMed
description The title compound, C(7)H(7)N·B(C(6)F(5))(3)·C(6)H(14), was obtained by the stoichiometric reaction of 2-vinyl­pyridine and tris­(penta­fluoro­phen­yl)borane in toluene. The formed adduct exhibits a restricted rotation along the B—N bond resulting in an asymmetry, which can be also observed in the (19)F NMR spectra. The B—N distance is equivalent to the distances found for 2-methyl­pyridine and 2-ethyl­pyridine B(C(6)F(5))(3) adducts. For the final refinement, the contributions of disordered solvent mol­ecules were removed from the diffraction data with SQUEEZE in PLATON [van der Sluis & Spek (1990). Acta Cryst. A46, 194–201; Spek (2009). Acta Cryst. D65, 148–155].
format Online
Article
Text
id pubmed-3344187
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33441872012-05-17 2-Vinyl­pyridine–tris­(penta­fluoro­phen­yl)borane hexane monosolvate Klahn, Marcus Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(7)N·B(C(6)F(5))(3)·C(6)H(14), was obtained by the stoichiometric reaction of 2-vinyl­pyridine and tris­(penta­fluoro­phen­yl)borane in toluene. The formed adduct exhibits a restricted rotation along the B—N bond resulting in an asymmetry, which can be also observed in the (19)F NMR spectra. The B—N distance is equivalent to the distances found for 2-methyl­pyridine and 2-ethyl­pyridine B(C(6)F(5))(3) adducts. For the final refinement, the contributions of disordered solvent mol­ecules were removed from the diffraction data with SQUEEZE in PLATON [van der Sluis & Spek (1990). Acta Cryst. A46, 194–201; Spek (2009). Acta Cryst. D65, 148–155]. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3344187/ /pubmed/22606190 http://dx.doi.org/10.1107/S1600536812013153 Text en © Klahn et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Klahn, Marcus
Spannenberg, Anke
Rosenthal, Uwe
2-Vinyl­pyridine–tris­(penta­fluoro­phen­yl)borane hexane monosolvate
title 2-Vinyl­pyridine–tris­(penta­fluoro­phen­yl)borane hexane monosolvate
title_full 2-Vinyl­pyridine–tris­(penta­fluoro­phen­yl)borane hexane monosolvate
title_fullStr 2-Vinyl­pyridine–tris­(penta­fluoro­phen­yl)borane hexane monosolvate
title_full_unstemmed 2-Vinyl­pyridine–tris­(penta­fluoro­phen­yl)borane hexane monosolvate
title_short 2-Vinyl­pyridine–tris­(penta­fluoro­phen­yl)borane hexane monosolvate
title_sort 2-vinyl­pyridine–tris­(penta­fluoro­phen­yl)borane hexane monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344187/
https://www.ncbi.nlm.nih.gov/pubmed/22606190
http://dx.doi.org/10.1107/S1600536812013153
work_keys_str_mv AT klahnmarcus 2vinylpyridinetrispentafluorophenylboranehexanemonosolvate
AT spannenberganke 2vinylpyridinetrispentafluorophenylboranehexanemonosolvate
AT rosenthaluwe 2vinylpyridinetrispentafluorophenylboranehexanemonosolvate

Ejemplares similares