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7′-Phenyl-1′,3′,5′,6′,7′,7a’-hexahydrodipiro[acenaphthylene-1,5′-pyrrolo[1,2-c]thiazole-6′,2′′-indane]-2,1′′(1H)-dione
In the title compound, C(31)H(23)NO(2)S, the pyrrolidine ring adopts an envelope conformation (with the spiro C atom as the flap), while the thiazolidine ring and the two cyclopentane rings adopt twisted conformations. The mean plane through the hexahydropyrrolo[1,2-c]thiazole ring [r.m.s devi...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344191/ https://www.ncbi.nlm.nih.gov/pubmed/22606194 http://dx.doi.org/10.1107/S1600536812013293 |
| _version_ | 1782231936236781568 |
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| author | Wei, Ang Chee Ali, Mohamed Ashraf Choon, Tan Soo Arshad, Suhana Razak, Ibrahim Abdul |
| author_facet | Wei, Ang Chee Ali, Mohamed Ashraf Choon, Tan Soo Arshad, Suhana Razak, Ibrahim Abdul |
| author_sort | Wei, Ang Chee |
| collection | PubMed |
| description | In the title compound, C(31)H(23)NO(2)S, the pyrrolidine ring adopts an envelope conformation (with the spiro C atom as the flap), while the thiazolidine ring and the two cyclopentane rings adopt twisted conformations. The mean plane through the hexahydropyrrolo[1,2-c]thiazole ring [r.m.s deviation = 0.400 (1) Å] forms dihedral angles of 76.83 (4), 80.70 (5) and 79.00 (4)° with the benzene ring and the mean planes of the dihydroacenaphthylene and the dihydroindene rings, respectively. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into sheets lying parallel to the bc plane. One of the ketone O atoms accepts three such bonds. Weak C—H⋯π interactions are also observed. |
| format | Online Article Text |
| id | pubmed-3344191 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33441912012-05-17 7′-Phenyl-1′,3′,5′,6′,7′,7a’-hexahydrodipiro[acenaphthylene-1,5′-pyrrolo[1,2-c]thiazole-6′,2′′-indane]-2,1′′(1H)-dione Wei, Ang Chee Ali, Mohamed Ashraf Choon, Tan Soo Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(23)NO(2)S, the pyrrolidine ring adopts an envelope conformation (with the spiro C atom as the flap), while the thiazolidine ring and the two cyclopentane rings adopt twisted conformations. The mean plane through the hexahydropyrrolo[1,2-c]thiazole ring [r.m.s deviation = 0.400 (1) Å] forms dihedral angles of 76.83 (4), 80.70 (5) and 79.00 (4)° with the benzene ring and the mean planes of the dihydroacenaphthylene and the dihydroindene rings, respectively. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into sheets lying parallel to the bc plane. One of the ketone O atoms accepts three such bonds. Weak C—H⋯π interactions are also observed. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3344191/ /pubmed/22606194 http://dx.doi.org/10.1107/S1600536812013293 Text en © Wei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Wei, Ang Chee Ali, Mohamed Ashraf Choon, Tan Soo Arshad, Suhana Razak, Ibrahim Abdul 7′-Phenyl-1′,3′,5′,6′,7′,7a’-hexahydrodipiro[acenaphthylene-1,5′-pyrrolo[1,2-c]thiazole-6′,2′′-indane]-2,1′′(1H)-dione |
| title | 7′-Phenyl-1′,3′,5′,6′,7′,7a’-hexahydrodipiro[acenaphthylene-1,5′-pyrrolo[1,2-c]thiazole-6′,2′′-indane]-2,1′′(1H)-dione |
| title_full | 7′-Phenyl-1′,3′,5′,6′,7′,7a’-hexahydrodipiro[acenaphthylene-1,5′-pyrrolo[1,2-c]thiazole-6′,2′′-indane]-2,1′′(1H)-dione |
| title_fullStr | 7′-Phenyl-1′,3′,5′,6′,7′,7a’-hexahydrodipiro[acenaphthylene-1,5′-pyrrolo[1,2-c]thiazole-6′,2′′-indane]-2,1′′(1H)-dione |
| title_full_unstemmed | 7′-Phenyl-1′,3′,5′,6′,7′,7a’-hexahydrodipiro[acenaphthylene-1,5′-pyrrolo[1,2-c]thiazole-6′,2′′-indane]-2,1′′(1H)-dione |
| title_short | 7′-Phenyl-1′,3′,5′,6′,7′,7a’-hexahydrodipiro[acenaphthylene-1,5′-pyrrolo[1,2-c]thiazole-6′,2′′-indane]-2,1′′(1H)-dione |
| title_sort | 7′-phenyl-1′,3′,5′,6′,7′,7a’-hexahydrodipiro[acenaphthylene-1,5′-pyrrolo[1,2-c]thiazole-6′,2′′-indane]-2,1′′(1h)-dione |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344191/ https://www.ncbi.nlm.nih.gov/pubmed/22606194 http://dx.doi.org/10.1107/S1600536812013293 |
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