(E)-3-Anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile

In the title acrylonitrile derivative, C(17)H(14)N(2)OS, the central amino­acryl­aldehyde O=C—C=C—NH unit, wherein an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif, is approximately planar, with an r.m.s. deviation of 0.0234 (2) Å for the five non-H atoms. This plane makes dihedra...

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Detalles Bibliográficos
Autores principales: Abdel-Aziz, Hatem A., Ghabbour, Hazem A., Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344195/
https://www.ncbi.nlm.nih.gov/pubmed/22606198
http://dx.doi.org/10.1107/S1600536812013475
Descripción
Sumario:In the title acrylonitrile derivative, C(17)H(14)N(2)OS, the central amino­acryl­aldehyde O=C—C=C—NH unit, wherein an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif, is approximately planar, with an r.m.s. deviation of 0.0234 (2) Å for the five non-H atoms. This plane makes dihedral angles of 41.04 (9) and 84.86 (10)° with the two phenyl rings. The dihedral angle between the two phenyl rings is 54.82 (10)°. An intra­molecular C—H⋯N hydrogen bond is also present. In the crystal, weak C—H⋯π and π–π inter­actions, with a centroid–centroid distance of 3.8526 (14) Å, are observed.

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