(E)-3-Anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile

In the title acrylonitrile derivative, C(17)H(14)N(2)OS, the central amino­acryl­aldehyde O=C—C=C—NH unit, wherein an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif, is approximately planar, with an r.m.s. deviation of 0.0234 (2) Å for the five non-H atoms. This plane makes dihedra...

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Autores principales: Abdel-Aziz, Hatem A., Ghabbour, Hazem A., Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344195/
https://www.ncbi.nlm.nih.gov/pubmed/22606198
http://dx.doi.org/10.1107/S1600536812013475
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author Abdel-Aziz, Hatem A.
Ghabbour, Hazem A.
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Abdel-Aziz, Hatem A.
Ghabbour, Hazem A.
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Abdel-Aziz, Hatem A.
collection PubMed
description In the title acrylonitrile derivative, C(17)H(14)N(2)OS, the central amino­acryl­aldehyde O=C—C=C—NH unit, wherein an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif, is approximately planar, with an r.m.s. deviation of 0.0234 (2) Å for the five non-H atoms. This plane makes dihedral angles of 41.04 (9) and 84.86 (10)° with the two phenyl rings. The dihedral angle between the two phenyl rings is 54.82 (10)°. An intra­molecular C—H⋯N hydrogen bond is also present. In the crystal, weak C—H⋯π and π–π inter­actions, with a centroid–centroid distance of 3.8526 (14) Å, are observed.
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spelling pubmed-33441952012-05-17 (E)-3-Anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile Abdel-Aziz, Hatem A. Ghabbour, Hazem A. Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title acrylonitrile derivative, C(17)H(14)N(2)OS, the central amino­acryl­aldehyde O=C—C=C—NH unit, wherein an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif, is approximately planar, with an r.m.s. deviation of 0.0234 (2) Å for the five non-H atoms. This plane makes dihedral angles of 41.04 (9) and 84.86 (10)° with the two phenyl rings. The dihedral angle between the two phenyl rings is 54.82 (10)°. An intra­molecular C—H⋯N hydrogen bond is also present. In the crystal, weak C—H⋯π and π–π inter­actions, with a centroid–centroid distance of 3.8526 (14) Å, are observed. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3344195/ /pubmed/22606198 http://dx.doi.org/10.1107/S1600536812013475 Text en © Abdel-Aziz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdel-Aziz, Hatem A.
Ghabbour, Hazem A.
Chantrapromma, Suchada
Fun, Hoong-Kun
(E)-3-Anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile
title (E)-3-Anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile
title_full (E)-3-Anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile
title_fullStr (E)-3-Anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile
title_full_unstemmed (E)-3-Anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile
title_short (E)-3-Anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile
title_sort (e)-3-anilino-2-benzoyl-3-(methyl­sulfan­yl)acrylonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344195/
https://www.ncbi.nlm.nih.gov/pubmed/22606198
http://dx.doi.org/10.1107/S1600536812013475
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