Trisodium scandium bis­(orthoborate)

Single crystals of tris­odium scandium bis­(orthoborate), Na(3)Sc(BO(3))(2), have been obtained by spontaneous crystallization from an Na(2)O–Sc(2)O(3)–B(2)O(3) melt. The crystal structure features a three-dimensional framework composed of planar [BO(3)](3−) groups and distorted ScO(6) octa­hedra wi...

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Autores principales: Fang, Jinzhi, Zhang, Xinyuan, Yao, Jiyong, Zhang, Guochun, Wang, Kunpeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344289/
https://www.ncbi.nlm.nih.gov/pubmed/22590055
http://dx.doi.org/10.1107/S1600536812015061
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author Fang, Jinzhi
Zhang, Xinyuan
Yao, Jiyong
Zhang, Guochun
Wang, Kunpeng
author_facet Fang, Jinzhi
Zhang, Xinyuan
Yao, Jiyong
Zhang, Guochun
Wang, Kunpeng
author_sort Fang, Jinzhi
collection PubMed
description Single crystals of tris­odium scandium bis­(orthoborate), Na(3)Sc(BO(3))(2), have been obtained by spontaneous crystallization from an Na(2)O–Sc(2)O(3)–B(2)O(3) melt. The crystal structure features a three-dimensional framework composed of planar [BO(3)](3−) groups and distorted ScO(6) octa­hedra with Na atoms in the cavities. The Sc atom occupies a special position (Wyckoff position 2b, site symmetry -1) and of the two Na atoms, one occupies a special position (Wyckoff position 2c, site symmetry -1).
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spelling pubmed-33442892012-05-15 Trisodium scandium bis­(orthoborate) Fang, Jinzhi Zhang, Xinyuan Yao, Jiyong Zhang, Guochun Wang, Kunpeng Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of tris­odium scandium bis­(orthoborate), Na(3)Sc(BO(3))(2), have been obtained by spontaneous crystallization from an Na(2)O–Sc(2)O(3)–B(2)O(3) melt. The crystal structure features a three-dimensional framework composed of planar [BO(3)](3−) groups and distorted ScO(6) octa­hedra with Na atoms in the cavities. The Sc atom occupies a special position (Wyckoff position 2b, site symmetry -1) and of the two Na atoms, one occupies a special position (Wyckoff position 2c, site symmetry -1). International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344289/ /pubmed/22590055 http://dx.doi.org/10.1107/S1600536812015061 Text en © Fang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Fang, Jinzhi
Zhang, Xinyuan
Yao, Jiyong
Zhang, Guochun
Wang, Kunpeng
Trisodium scandium bis­(orthoborate)
title Trisodium scandium bis­(orthoborate)
title_full Trisodium scandium bis­(orthoborate)
title_fullStr Trisodium scandium bis­(orthoborate)
title_full_unstemmed Trisodium scandium bis­(orthoborate)
title_short Trisodium scandium bis­(orthoborate)
title_sort trisodium scandium bis­(orthoborate)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344289/
https://www.ncbi.nlm.nih.gov/pubmed/22590055
http://dx.doi.org/10.1107/S1600536812015061
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AT zhangxinyuan trisodiumscandiumbisorthoborate
AT yaojiyong trisodiumscandiumbisorthoborate
AT zhangguochun trisodiumscandiumbisorthoborate
AT wangkunpeng trisodiumscandiumbisorthoborate

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