Poly[[diaqua­hexa-μ-cyanido-cerium(III)ferrate(III)] dihydrate]

In the structure of the title complex, {[CeFe(CN)(6)(H(2)O)(2)]·2H(2)O}(n), the Ce(III) and Fe(III) atoms exhibit square anti­prismatic [CeN(6)(H(2)O)(2)] (site symmetry m2m) and octahedral [FeC(6)] (site symmetry 2/m) coordination geometries, respectively. The metal atoms are linked alternately thr...

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Detalles Bibliográficos
Autores principales: Yu, Deng-Yong, Liu, Xiao-Qing, Yuan, Ai-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344291/
https://www.ncbi.nlm.nih.gov/pubmed/22590057
http://dx.doi.org/10.1107/S1600536812016911
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author Yu, Deng-Yong
Liu, Xiao-Qing
Yuan, Ai-Hua
author_facet Yu, Deng-Yong
Liu, Xiao-Qing
Yuan, Ai-Hua
author_sort Yu, Deng-Yong
collection PubMed
description In the structure of the title complex, {[CeFe(CN)(6)(H(2)O)(2)]·2H(2)O}(n), the Ce(III) and Fe(III) atoms exhibit square anti­prismatic [CeN(6)(H(2)O)(2)] (site symmetry m2m) and octahedral [FeC(6)] (site symmetry 2/m) coordination geometries, respectively. The metal atoms are linked alternately through the cyanide groups, forming a three-dimensional framework in which the {Ce(2)Fe(2)(CN)(4)} puckered square unit is the basic building block. The crystal packing is enforced by O—H⋯O and O—H⋯N hydrogen bonds, including the uncoordinated water molecule which is located on a mirror plane.
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spelling pubmed-33442912012-05-15 Poly[[diaqua­hexa-μ-cyanido-cerium(III)ferrate(III)] dihydrate] Yu, Deng-Yong Liu, Xiao-Qing Yuan, Ai-Hua Acta Crystallogr Sect E Struct Rep Online Inorganic Papers In the structure of the title complex, {[CeFe(CN)(6)(H(2)O)(2)]·2H(2)O}(n), the Ce(III) and Fe(III) atoms exhibit square anti­prismatic [CeN(6)(H(2)O)(2)] (site symmetry m2m) and octahedral [FeC(6)] (site symmetry 2/m) coordination geometries, respectively. The metal atoms are linked alternately through the cyanide groups, forming a three-dimensional framework in which the {Ce(2)Fe(2)(CN)(4)} puckered square unit is the basic building block. The crystal packing is enforced by O—H⋯O and O—H⋯N hydrogen bonds, including the uncoordinated water molecule which is located on a mirror plane. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344291/ /pubmed/22590057 http://dx.doi.org/10.1107/S1600536812016911 Text en © Yu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Yu, Deng-Yong
Liu, Xiao-Qing
Yuan, Ai-Hua
Poly[[diaqua­hexa-μ-cyanido-cerium(III)ferrate(III)] dihydrate]
title Poly[[diaqua­hexa-μ-cyanido-cerium(III)ferrate(III)] dihydrate]
title_full Poly[[diaqua­hexa-μ-cyanido-cerium(III)ferrate(III)] dihydrate]
title_fullStr Poly[[diaqua­hexa-μ-cyanido-cerium(III)ferrate(III)] dihydrate]
title_full_unstemmed Poly[[diaqua­hexa-μ-cyanido-cerium(III)ferrate(III)] dihydrate]
title_short Poly[[diaqua­hexa-μ-cyanido-cerium(III)ferrate(III)] dihydrate]
title_sort poly[[diaqua­hexa-μ-cyanido-cerium(iii)ferrate(iii)] dihydrate]
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344291/
https://www.ncbi.nlm.nih.gov/pubmed/22590057
http://dx.doi.org/10.1107/S1600536812016911
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AT liuxiaoqing polydiaquahexamcyanidoceriumiiiferrateiiidihydrate
AT yuanaihua polydiaquahexamcyanidoceriumiiiferrateiiidihydrate

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