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Poly[[diaqua[μ(2)-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ(4)-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate]
In the title compound, {[Ce(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))(H(2)O)(2)]·H(2)O}(n), three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce(III) cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not de...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344292/ https://www.ncbi.nlm.nih.gov/pubmed/22590058 http://dx.doi.org/10.1107/S1600536812013402 |
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author | Deng, Yi-Fang Nie, Xue |
author_facet | Deng, Yi-Fang Nie, Xue |
author_sort | Deng, Yi-Fang |
collection | PubMed |
description | In the title compound, {[Ce(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))(H(2)O)(2)]·H(2)O}(n), three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce(III) cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not deprotonated and links with the adjacent pyridine ring via an O—H⋯N hydrogen bond. The Ce(III) cation is coordinated by six O atoms from carboxyl groups and two O atoms from coordinated water molecules in a distorted square-antiprismatic arrangement. Extensive O—H⋯O and O—H⋯N hydrogen bonding occurs in the crystal structure. |
format | Online Article Text |
id | pubmed-3344292 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33442922012-05-15 Poly[[diaqua[μ(2)-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ(4)-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate] Deng, Yi-Fang Nie, Xue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ce(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))(H(2)O)(2)]·H(2)O}(n), three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce(III) cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not deprotonated and links with the adjacent pyridine ring via an O—H⋯N hydrogen bond. The Ce(III) cation is coordinated by six O atoms from carboxyl groups and two O atoms from coordinated water molecules in a distorted square-antiprismatic arrangement. Extensive O—H⋯O and O—H⋯N hydrogen bonding occurs in the crystal structure. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344292/ /pubmed/22590058 http://dx.doi.org/10.1107/S1600536812013402 Text en © Deng and Nie 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Deng, Yi-Fang Nie, Xue Poly[[diaqua[μ(2)-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ(4)-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate] |
title | Poly[[diaqua[μ(2)-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ(4)-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate] |
title_full | Poly[[diaqua[μ(2)-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ(4)-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate] |
title_fullStr | Poly[[diaqua[μ(2)-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ(4)-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate] |
title_full_unstemmed | Poly[[diaqua[μ(2)-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ(4)-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate] |
title_short | Poly[[diaqua[μ(2)-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ(4)-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate] |
title_sort | poly[[diaqua[μ(2)-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ(4)-5-(pyridine-4-carboxamido)isophthalato]cerium(iii)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344292/ https://www.ncbi.nlm.nih.gov/pubmed/22590058 http://dx.doi.org/10.1107/S1600536812013402 |
work_keys_str_mv | AT dengyifang polydiaquam23carboxy5pyridine4carboxamidobenzoatom45pyridine4carboxamidoisophthalatoceriumiiimonohydrate AT niexue polydiaquam23carboxy5pyridine4carboxamidobenzoatom45pyridine4carboxamidoisophthalatoceriumiiimonohydrate |