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Poly[[diaqua­[μ(2)-3-carb­oxy-5-(pyridine-4-carboxamido)­benzoato][μ(4)-5-(pyridine-4-carboxamido)­isophthalato]cerium(III)] monohydrate]

In the title compound, {[Ce(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))(H(2)O)(2)]·H(2)O}(n), three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce(III) cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not de...

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Detalles Bibliográficos
Autores principales: Deng, Yi-Fang, Nie, Xue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344292/
https://www.ncbi.nlm.nih.gov/pubmed/22590058
http://dx.doi.org/10.1107/S1600536812013402
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author Deng, Yi-Fang
Nie, Xue
author_facet Deng, Yi-Fang
Nie, Xue
author_sort Deng, Yi-Fang
collection PubMed
description In the title compound, {[Ce(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))(H(2)O)(2)]·H(2)O}(n), three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce(III) cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not deprotonated and links with the adjacent pyridine ring via an O—H⋯N hydrogen bond. The Ce(III) cation is coordinated by six O atoms from carboxyl groups and two O atoms from coordinated water mol­ecules in a distorted square-anti­prismatic arrangement. Extensive O—H⋯O and O—H⋯N hydrogen bonding occurs in the crystal structure.
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spelling pubmed-33442922012-05-15 Poly[[diaqua­[μ(2)-3-carb­oxy-5-(pyridine-4-carboxamido)­benzoato][μ(4)-5-(pyridine-4-carboxamido)­isophthalato]cerium(III)] monohydrate] Deng, Yi-Fang Nie, Xue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ce(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))(H(2)O)(2)]·H(2)O}(n), three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce(III) cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not deprotonated and links with the adjacent pyridine ring via an O—H⋯N hydrogen bond. The Ce(III) cation is coordinated by six O atoms from carboxyl groups and two O atoms from coordinated water mol­ecules in a distorted square-anti­prismatic arrangement. Extensive O—H⋯O and O—H⋯N hydrogen bonding occurs in the crystal structure. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344292/ /pubmed/22590058 http://dx.doi.org/10.1107/S1600536812013402 Text en © Deng and Nie 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Yi-Fang
Nie, Xue
Poly[[diaqua­[μ(2)-3-carb­oxy-5-(pyridine-4-carboxamido)­benzoato][μ(4)-5-(pyridine-4-carboxamido)­isophthalato]cerium(III)] monohydrate]
title Poly[[diaqua­[μ(2)-3-carb­oxy-5-(pyridine-4-carboxamido)­benzoato][μ(4)-5-(pyridine-4-carboxamido)­isophthalato]cerium(III)] monohydrate]
title_full Poly[[diaqua­[μ(2)-3-carb­oxy-5-(pyridine-4-carboxamido)­benzoato][μ(4)-5-(pyridine-4-carboxamido)­isophthalato]cerium(III)] monohydrate]
title_fullStr Poly[[diaqua­[μ(2)-3-carb­oxy-5-(pyridine-4-carboxamido)­benzoato][μ(4)-5-(pyridine-4-carboxamido)­isophthalato]cerium(III)] monohydrate]
title_full_unstemmed Poly[[diaqua­[μ(2)-3-carb­oxy-5-(pyridine-4-carboxamido)­benzoato][μ(4)-5-(pyridine-4-carboxamido)­isophthalato]cerium(III)] monohydrate]
title_short Poly[[diaqua­[μ(2)-3-carb­oxy-5-(pyridine-4-carboxamido)­benzoato][μ(4)-5-(pyridine-4-carboxamido)­isophthalato]cerium(III)] monohydrate]
title_sort poly[[diaqua­[μ(2)-3-carb­oxy-5-(pyridine-4-carboxamido)­benzoato][μ(4)-5-(pyridine-4-carboxamido)­isophthalato]cerium(iii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344292/
https://www.ncbi.nlm.nih.gov/pubmed/22590058
http://dx.doi.org/10.1107/S1600536812013402
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AT niexue polydiaquam23carboxy5pyridine4carboxamidobenzoatom45pyridine4carboxamidoisophthalatoceriumiiimonohydrate