Tris(1,10-phenanthroline-κ(2) N,N′)iron(II) bis­[(1,10-phenanthroline-κ(2) N,N′)tetra­kis­(thio­cyanato-κN)chromate(III)] acetonitrile tris­olvate monohydrate

Single crystals of the title heterometallic compound, [Fe(C(12)H(8)N(2))(3)][Cr(NCS)(4)(C(12)H(8)N(2))](2)·3CH(3)CN·H(2)O or [Fe(Cphen)(3)][Cr(NCS)(4)(phen)](2)·3CH(3)CN·H(2)O, were pre­pared using the one-pot open-air reaction of iron powder, Reineckes salt and 1,10-phenanthroline (phen) in acetoni...

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Detalles Bibliográficos
Autores principales: Semenaka, Valentyna V., Nesterova, Oksana V., Kokozay, Volodymyr N., Bon, Volodymyr V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344293/
https://www.ncbi.nlm.nih.gov/pubmed/22590059
http://dx.doi.org/10.1107/S1600536812012949
Descripción
Sumario:Single crystals of the title heterometallic compound, [Fe(C(12)H(8)N(2))(3)][Cr(NCS)(4)(C(12)H(8)N(2))](2)·3CH(3)CN·H(2)O or [Fe(Cphen)(3)][Cr(NCS)(4)(phen)](2)·3CH(3)CN·H(2)O, were pre­pared using the one-pot open-air reaction of iron powder, Reineckes salt and 1,10-phenanthroline (phen) in acetonitrile. The asymetric unit consists of an [Fe(phen)(3)](2+) cation, two [Cr(phen)(NCS)(4)](−) anions, three acetonitrile solvent mol­ecules and a water mol­ecule. The Fe and Cr atoms both show a slightly distorted octa­hedral FeN(6) and CrN(6) coordination geometry with adjacent angles in the range 79.67 (12)–95.21 (12)°. No classical hydrogen bonding involving the water molecule is observed.

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