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Tris(1,10-phenanthroline-κ(2) N,N′)iron(II) bis[(1,10-phenanthroline-κ(2) N,N′)tetrakis(thiocyanato-κN)chromate(III)] acetonitrile trisolvate monohydrate
Single crystals of the title heterometallic compound, [Fe(C(12)H(8)N(2))(3)][Cr(NCS)(4)(C(12)H(8)N(2))](2)·3CH(3)CN·H(2)O or [Fe(Cphen)(3)][Cr(NCS)(4)(phen)](2)·3CH(3)CN·H(2)O, were prepared using the one-pot open-air reaction of iron powder, Reineckes salt and 1,10-phenanthroline (phen) in acetoni...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344293/ https://www.ncbi.nlm.nih.gov/pubmed/22590059 http://dx.doi.org/10.1107/S1600536812012949 |
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| author | Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Volodymyr N. Bon, Volodymyr V. |
| author_facet | Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Volodymyr N. Bon, Volodymyr V. |
| author_sort | Semenaka, Valentyna V. |
| collection | PubMed |
| description | Single crystals of the title heterometallic compound, [Fe(C(12)H(8)N(2))(3)][Cr(NCS)(4)(C(12)H(8)N(2))](2)·3CH(3)CN·H(2)O or [Fe(Cphen)(3)][Cr(NCS)(4)(phen)](2)·3CH(3)CN·H(2)O, were prepared using the one-pot open-air reaction of iron powder, Reineckes salt and 1,10-phenanthroline (phen) in acetonitrile. The asymetric unit consists of an [Fe(phen)(3)](2+) cation, two [Cr(phen)(NCS)(4)](−) anions, three acetonitrile solvent molecules and a water molecule. The Fe and Cr atoms both show a slightly distorted octahedral FeN(6) and CrN(6) coordination geometry with adjacent angles in the range 79.67 (12)–95.21 (12)°. No classical hydrogen bonding involving the water molecule is observed. |
| format | Online Article Text |
| id | pubmed-3344293 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33442932012-05-15 Tris(1,10-phenanthroline-κ(2) N,N′)iron(II) bis[(1,10-phenanthroline-κ(2) N,N′)tetrakis(thiocyanato-κN)chromate(III)] acetonitrile trisolvate monohydrate Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Volodymyr N. Bon, Volodymyr V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Single crystals of the title heterometallic compound, [Fe(C(12)H(8)N(2))(3)][Cr(NCS)(4)(C(12)H(8)N(2))](2)·3CH(3)CN·H(2)O or [Fe(Cphen)(3)][Cr(NCS)(4)(phen)](2)·3CH(3)CN·H(2)O, were prepared using the one-pot open-air reaction of iron powder, Reineckes salt and 1,10-phenanthroline (phen) in acetonitrile. The asymetric unit consists of an [Fe(phen)(3)](2+) cation, two [Cr(phen)(NCS)(4)](−) anions, three acetonitrile solvent molecules and a water molecule. The Fe and Cr atoms both show a slightly distorted octahedral FeN(6) and CrN(6) coordination geometry with adjacent angles in the range 79.67 (12)–95.21 (12)°. No classical hydrogen bonding involving the water molecule is observed. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344293/ /pubmed/22590059 http://dx.doi.org/10.1107/S1600536812012949 Text en © Semenaka et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Volodymyr N. Bon, Volodymyr V. Tris(1,10-phenanthroline-κ(2) N,N′)iron(II) bis[(1,10-phenanthroline-κ(2) N,N′)tetrakis(thiocyanato-κN)chromate(III)] acetonitrile trisolvate monohydrate |
| title | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis[(1,10-phenanthroline-κ(2)
N,N′)tetrakis(thiocyanato-κN)chromate(III)] acetonitrile trisolvate monohydrate |
| title_full | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis[(1,10-phenanthroline-κ(2)
N,N′)tetrakis(thiocyanato-κN)chromate(III)] acetonitrile trisolvate monohydrate |
| title_fullStr | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis[(1,10-phenanthroline-κ(2)
N,N′)tetrakis(thiocyanato-κN)chromate(III)] acetonitrile trisolvate monohydrate |
| title_full_unstemmed | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis[(1,10-phenanthroline-κ(2)
N,N′)tetrakis(thiocyanato-κN)chromate(III)] acetonitrile trisolvate monohydrate |
| title_short | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis[(1,10-phenanthroline-κ(2)
N,N′)tetrakis(thiocyanato-κN)chromate(III)] acetonitrile trisolvate monohydrate |
| title_sort | tris(1,10-phenanthroline-κ(2)
n,n′)iron(ii) bis[(1,10-phenanthroline-κ(2)
n,n′)tetrakis(thiocyanato-κn)chromate(iii)] acetonitrile trisolvate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344293/ https://www.ncbi.nlm.nih.gov/pubmed/22590059 http://dx.doi.org/10.1107/S1600536812012949 |
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