{S-Benzyl 3-[(6-methyl­pyridin-2-yl-κN)methyl­idene]dithio­carbazato-κ(2) N (3),S}zinc

The title compound, [Zn(C(15)H(14)N(3)S(2))(2)], contains two chemically equivalent Schiff base anions that are coordinated to the Zn(II) ion as tridentate N,N′,S-chelating ligands, creating a distorted octa­hedral environment [the smallest angle being 75.40 (6)° and the widest angle being 162.87 (6...

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Detalles Bibliográficos
Autores principales: Ravoof, Thahira B. S. A., Omar, Siti Aminah, Mohamed Tahir, Mohamed Ibrahim, Crouse, Karen A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344295/
https://www.ncbi.nlm.nih.gov/pubmed/22590061
http://dx.doi.org/10.1107/S1600536812013529
Descripción
Sumario:The title compound, [Zn(C(15)H(14)N(3)S(2))(2)], contains two chemically equivalent Schiff base anions that are coordinated to the Zn(II) ion as tridentate N,N′,S-chelating ligands, creating a distorted octa­hedral environment [the smallest angle being 75.40 (6)° and the widest angle being 162.87 (6)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 85.65 (5)°. Weak C—H⋯S hydrogen bonds are also observed.

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