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trans-Dichloridobis(quinoline-κN)platinum(II)
In the title complex, trans-[PtCl(2)(C(9)H(7)N)(2)], the Pt(II) ion is four-coordinated in an essentially square-planar coordination environment defined by two N atoms from two quinoline (qu) ligands and two Cl(−) anions. The Pt atom is located on an inversion centre and thus the asymmetric unit con...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344296/ https://www.ncbi.nlm.nih.gov/pubmed/22590062 http://dx.doi.org/10.1107/S1600536812013608 |
Sumario: | In the title complex, trans-[PtCl(2)(C(9)H(7)N)(2)], the Pt(II) ion is four-coordinated in an essentially square-planar coordination environment defined by two N atoms from two quinoline (qu) ligands and two Cl(−) anions. The Pt atom is located on an inversion centre and thus the asymmetric unit contains one half of the complex; the PtN(2)Cl(2) unit is exactly planar. The dihedral angle between the PtN(2)Cl(2) unit and the quinoline ligand is 85.1 (1)°. In the crystal, the complex molecules are stacked into columns along the b axis. In the columns, several intermolecular π–π interactions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.733 (5) Å between pyridine rings. |
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