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Poly[aqua(μ(3)-5-azaniumylisophthalato)(μ-oxalato)neodymium(III)]
The title compound, [Nd(C(8)H(6)NO(4))(C(2)O(4))(H(2)O)](n), is a layer-like coordination polymer. The Nd(III) ion is coordinated by four carboxylate O atoms from three bridging 5-azaniumylisophthalate (Haip) ligands, four carboxylate O atoms from two oxalate (ox) anions and one ligated water m...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344297/ https://www.ncbi.nlm.nih.gov/pubmed/22590063 http://dx.doi.org/10.1107/S1600536812013554 |
Sumario: | The title compound, [Nd(C(8)H(6)NO(4))(C(2)O(4))(H(2)O)](n), is a layer-like coordination polymer. The Nd(III) ion is coordinated by four carboxylate O atoms from three bridging 5-azaniumylisophthalate (Haip) ligands, four carboxylate O atoms from two oxalate (ox) anions and one ligated water molecule in a tricapped trigonal–prismatic geometry. The Haip anion acts as a μ(3)-bridge, connecting three Nd(III) ions through two carboxylate groups; the ox anion adopts a bis-bidentate-bridging mode, linking two Nd(III) ions. The layer framework is further extended to a three-dimensional supramolecular structure through N—H⋯O and O—H⋯O hydrogen bonds. |
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