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Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ(3) O,N (2),S]nickel(II) dimethylformamide monosolvate
The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex molecule and one disordered dimethylformamide solvent molecule. The Ni(II) ion is six-coordinated in a distorted octahedral geometry by two N, two O and two S atoms. An intramolecular C—...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344298/ https://www.ncbi.nlm.nih.gov/pubmed/22590064 http://dx.doi.org/10.1107/S1600536812012834 |
Sumario: | The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex molecule and one disordered dimethylformamide solvent molecule. The Ni(II) ion is six-coordinated in a distorted octahedral geometry by two N, two O and two S atoms. An intramolecular C—H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked through intermolecular N—H⋯S, N—H⋯O, C—H⋯N, C—H⋯O and C—H⋯S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C—H⋯π interactions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514 (15):0.486 (15) ratio. |
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