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Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ(3) O,N (2),S]nickel(II) dimethylformamide monosolvate
The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex molecule and one disordered dimethylformamide solvent molecule. The Ni(II) ion is six-coordinated in a distorted octahedral geometry by two N, two O and two S atoms. An intramolecular C—...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344298/ https://www.ncbi.nlm.nih.gov/pubmed/22590064 http://dx.doi.org/10.1107/S1600536812012834 |
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author | Ali, Amna Qasem Eltayeb, Naser Eltaher Teoh, Siang Guan Salhin, Abdussalam Fun, Hoong-Kun |
author_facet | Ali, Amna Qasem Eltayeb, Naser Eltaher Teoh, Siang Guan Salhin, Abdussalam Fun, Hoong-Kun |
author_sort | Ali, Amna Qasem |
collection | PubMed |
description | The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex molecule and one disordered dimethylformamide solvent molecule. The Ni(II) ion is six-coordinated in a distorted octahedral geometry by two N, two O and two S atoms. An intramolecular C—H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked through intermolecular N—H⋯S, N—H⋯O, C—H⋯N, C—H⋯O and C—H⋯S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C—H⋯π interactions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514 (15):0.486 (15) ratio. |
format | Online Article Text |
id | pubmed-3344298 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33442982012-05-15 Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ(3) O,N (2),S]nickel(II) dimethylformamide monosolvate Ali, Amna Qasem Eltayeb, Naser Eltaher Teoh, Siang Guan Salhin, Abdussalam Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex molecule and one disordered dimethylformamide solvent molecule. The Ni(II) ion is six-coordinated in a distorted octahedral geometry by two N, two O and two S atoms. An intramolecular C—H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked through intermolecular N—H⋯S, N—H⋯O, C—H⋯N, C—H⋯O and C—H⋯S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C—H⋯π interactions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514 (15):0.486 (15) ratio. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344298/ /pubmed/22590064 http://dx.doi.org/10.1107/S1600536812012834 Text en © Ali et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ali, Amna Qasem Eltayeb, Naser Eltaher Teoh, Siang Guan Salhin, Abdussalam Fun, Hoong-Kun Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ(3) O,N (2),S]nickel(II) dimethylformamide monosolvate |
title | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ(3)
O,N
(2),S]nickel(II) dimethylformamide monosolvate |
title_full | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ(3)
O,N
(2),S]nickel(II) dimethylformamide monosolvate |
title_fullStr | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ(3)
O,N
(2),S]nickel(II) dimethylformamide monosolvate |
title_full_unstemmed | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ(3)
O,N
(2),S]nickel(II) dimethylformamide monosolvate |
title_short | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ(3)
O,N
(2),S]nickel(II) dimethylformamide monosolvate |
title_sort | bis[2-(2-oxoindolin-3-ylidene)-n-phenylhydrazinecarbothioamidato-κ(3)
o,n
(2),s]nickel(ii) dimethylformamide monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344298/ https://www.ncbi.nlm.nih.gov/pubmed/22590064 http://dx.doi.org/10.1107/S1600536812012834 |
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