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Bis[2-(2-oxoindolin-3-yl­idene)-N-phenylhydrazinecarbothio­amidato-κ(3) O,N (2),S]nickel(II) dimethyl­formamide monosolvate

The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex mol­ecule and one disordered dimethyl­formamide solvent mol­ecule. The Ni(II) ion is six-coordinated in a distorted octa­hedral geometry by two N, two O and two S atoms. An intra­molecular C—...

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Autores principales: Ali, Amna Qasem, Eltayeb, Naser Eltaher, Teoh, Siang Guan, Salhin, Abdussalam, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344298/
https://www.ncbi.nlm.nih.gov/pubmed/22590064
http://dx.doi.org/10.1107/S1600536812012834
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author Ali, Amna Qasem
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Salhin, Abdussalam
Fun, Hoong-Kun
author_facet Ali, Amna Qasem
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Salhin, Abdussalam
Fun, Hoong-Kun
author_sort Ali, Amna Qasem
collection PubMed
description The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex mol­ecule and one disordered dimethyl­formamide solvent mol­ecule. The Ni(II) ion is six-coordinated in a distorted octa­hedral geometry by two N, two O and two S atoms. An intra­molecular C—H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked through inter­molecular N—H⋯S, N—H⋯O, C—H⋯N, C—H⋯O and C—H⋯S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C—H⋯π inter­actions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514 (15):0.486 (15) ratio.
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spelling pubmed-33442982012-05-15 Bis[2-(2-oxoindolin-3-yl­idene)-N-phenylhydrazinecarbothio­amidato-κ(3) O,N (2),S]nickel(II) dimethyl­formamide monosolvate Ali, Amna Qasem Eltayeb, Naser Eltaher Teoh, Siang Guan Salhin, Abdussalam Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(15)H(11)N(4)OS)(2)]·C(3)H(7)NO, contains one Ni(II) complex mol­ecule and one disordered dimethyl­formamide solvent mol­ecule. The Ni(II) ion is six-coordinated in a distorted octa­hedral geometry by two N, two O and two S atoms. An intra­molecular C—H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked through inter­molecular N—H⋯S, N—H⋯O, C—H⋯N, C—H⋯O and C—H⋯S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C—H⋯π inter­actions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514 (15):0.486 (15) ratio. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344298/ /pubmed/22590064 http://dx.doi.org/10.1107/S1600536812012834 Text en © Ali et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ali, Amna Qasem
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Salhin, Abdussalam
Fun, Hoong-Kun
Bis[2-(2-oxoindolin-3-yl­idene)-N-phenylhydrazinecarbothio­amidato-κ(3) O,N (2),S]nickel(II) dimethyl­formamide monosolvate
title Bis[2-(2-oxoindolin-3-yl­idene)-N-phenylhydrazinecarbothio­amidato-κ(3) O,N (2),S]nickel(II) dimethyl­formamide monosolvate
title_full Bis[2-(2-oxoindolin-3-yl­idene)-N-phenylhydrazinecarbothio­amidato-κ(3) O,N (2),S]nickel(II) dimethyl­formamide monosolvate
title_fullStr Bis[2-(2-oxoindolin-3-yl­idene)-N-phenylhydrazinecarbothio­amidato-κ(3) O,N (2),S]nickel(II) dimethyl­formamide monosolvate
title_full_unstemmed Bis[2-(2-oxoindolin-3-yl­idene)-N-phenylhydrazinecarbothio­amidato-κ(3) O,N (2),S]nickel(II) dimethyl­formamide monosolvate
title_short Bis[2-(2-oxoindolin-3-yl­idene)-N-phenylhydrazinecarbothio­amidato-κ(3) O,N (2),S]nickel(II) dimethyl­formamide monosolvate
title_sort bis[2-(2-oxoindolin-3-yl­idene)-n-phenylhydrazinecarbothio­amidato-κ(3) o,n (2),s]nickel(ii) dimethyl­formamide monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344298/
https://www.ncbi.nlm.nih.gov/pubmed/22590064
http://dx.doi.org/10.1107/S1600536812012834
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