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Poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(III)] monohydrate]

In the title compound, {[Nd(3)(C(7)H(3)NO(4))(3)(OH)(3)]·H(2)O}(n), the Nd(III) atom is eight-coordinated by the three O atoms of three asymmetrically μ(3)-bridging hydroxide groups, by four carboxyl­ate O atoms of four different pyridine-2,5-dicarboxyl­ate (2,5-pydc) ligands, and by the N atom of a...

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Detalles Bibliográficos
Autores principales: Zhang, Qing, Wang, Xing, Wang, Shen-Tang, Liu, Chun-Bo, Che, Guang-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344300/
https://www.ncbi.nlm.nih.gov/pubmed/22590066
http://dx.doi.org/10.1107/S160053681201286X
Descripción
Sumario:In the title compound, {[Nd(3)(C(7)H(3)NO(4))(3)(OH)(3)]·H(2)O}(n), the Nd(III) atom is eight-coordinated by the three O atoms of three asymmetrically μ(3)-bridging hydroxide groups, by four carboxyl­ate O atoms of four different pyridine-2,5-dicarboxyl­ate (2,5-pydc) ligands, and by the N atom of a 2,5-pydc ligand. Six Nd atoms are connected by six hydroxide groups, forming an [Nd(6)(μ(3)-OH)(6)] cluster unit of symmetry -3 and a slightly compressed octa­hedral geometry. Adjacent [Nd(6)(μ(3)-OH)(6)] clusters are connected by the 2,5-pydc ligands, via O and N atoms, forming chains along the c axis. The remaining O atoms of the 2,5-pydc ligands link these chains into a three-dimensional framework. A disordered water molecule, located on a threefold rotation axis at the opposite side of the [Nd(6)(μ(3)-OH)(6)] cluster and exposed to each of the three Nd atoms, completes the structure.