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Poly[[tri-μ(3)-hydroxido-tris(μ(4)-pyridine-2,5-dicarboxylato)trineodymium(III)] monohydrate]
In the title compound, {[Nd(3)(C(7)H(3)NO(4))(3)(OH)(3)]·H(2)O}(n), the Nd(III) atom is eight-coordinated by the three O atoms of three asymmetrically μ(3)-bridging hydroxide groups, by four carboxylate O atoms of four different pyridine-2,5-dicarboxylate (2,5-pydc) ligands, and by the N atom of a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344300/ https://www.ncbi.nlm.nih.gov/pubmed/22590066 http://dx.doi.org/10.1107/S160053681201286X |
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author | Zhang, Qing Wang, Xing Wang, Shen-Tang Liu, Chun-Bo Che, Guang-Bo |
author_facet | Zhang, Qing Wang, Xing Wang, Shen-Tang Liu, Chun-Bo Che, Guang-Bo |
author_sort | Zhang, Qing |
collection | PubMed |
description | In the title compound, {[Nd(3)(C(7)H(3)NO(4))(3)(OH)(3)]·H(2)O}(n), the Nd(III) atom is eight-coordinated by the three O atoms of three asymmetrically μ(3)-bridging hydroxide groups, by four carboxylate O atoms of four different pyridine-2,5-dicarboxylate (2,5-pydc) ligands, and by the N atom of a 2,5-pydc ligand. Six Nd atoms are connected by six hydroxide groups, forming an [Nd(6)(μ(3)-OH)(6)] cluster unit of symmetry -3 and a slightly compressed octahedral geometry. Adjacent [Nd(6)(μ(3)-OH)(6)] clusters are connected by the 2,5-pydc ligands, via O and N atoms, forming chains along the c axis. The remaining O atoms of the 2,5-pydc ligands link these chains into a three-dimensional framework. A disordered water molecule, located on a threefold rotation axis at the opposite side of the [Nd(6)(μ(3)-OH)(6)] cluster and exposed to each of the three Nd atoms, completes the structure. |
format | Online Article Text |
id | pubmed-3344300 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443002012-05-15 Poly[[tri-μ(3)-hydroxido-tris(μ(4)-pyridine-2,5-dicarboxylato)trineodymium(III)] monohydrate] Zhang, Qing Wang, Xing Wang, Shen-Tang Liu, Chun-Bo Che, Guang-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Nd(3)(C(7)H(3)NO(4))(3)(OH)(3)]·H(2)O}(n), the Nd(III) atom is eight-coordinated by the three O atoms of three asymmetrically μ(3)-bridging hydroxide groups, by four carboxylate O atoms of four different pyridine-2,5-dicarboxylate (2,5-pydc) ligands, and by the N atom of a 2,5-pydc ligand. Six Nd atoms are connected by six hydroxide groups, forming an [Nd(6)(μ(3)-OH)(6)] cluster unit of symmetry -3 and a slightly compressed octahedral geometry. Adjacent [Nd(6)(μ(3)-OH)(6)] clusters are connected by the 2,5-pydc ligands, via O and N atoms, forming chains along the c axis. The remaining O atoms of the 2,5-pydc ligands link these chains into a three-dimensional framework. A disordered water molecule, located on a threefold rotation axis at the opposite side of the [Nd(6)(μ(3)-OH)(6)] cluster and exposed to each of the three Nd atoms, completes the structure. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344300/ /pubmed/22590066 http://dx.doi.org/10.1107/S160053681201286X Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Qing Wang, Xing Wang, Shen-Tang Liu, Chun-Bo Che, Guang-Bo Poly[[tri-μ(3)-hydroxido-tris(μ(4)-pyridine-2,5-dicarboxylato)trineodymium(III)] monohydrate] |
title | Poly[[tri-μ(3)-hydroxido-tris(μ(4)-pyridine-2,5-dicarboxylato)trineodymium(III)] monohydrate] |
title_full | Poly[[tri-μ(3)-hydroxido-tris(μ(4)-pyridine-2,5-dicarboxylato)trineodymium(III)] monohydrate] |
title_fullStr | Poly[[tri-μ(3)-hydroxido-tris(μ(4)-pyridine-2,5-dicarboxylato)trineodymium(III)] monohydrate] |
title_full_unstemmed | Poly[[tri-μ(3)-hydroxido-tris(μ(4)-pyridine-2,5-dicarboxylato)trineodymium(III)] monohydrate] |
title_short | Poly[[tri-μ(3)-hydroxido-tris(μ(4)-pyridine-2,5-dicarboxylato)trineodymium(III)] monohydrate] |
title_sort | poly[[tri-μ(3)-hydroxido-tris(μ(4)-pyridine-2,5-dicarboxylato)trineodymium(iii)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344300/ https://www.ncbi.nlm.nih.gov/pubmed/22590066 http://dx.doi.org/10.1107/S160053681201286X |
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