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Poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(III)] monohydrate]

In the title compound, {[Nd(3)(C(7)H(3)NO(4))(3)(OH)(3)]·H(2)O}(n), the Nd(III) atom is eight-coordinated by the three O atoms of three asymmetrically μ(3)-bridging hydroxide groups, by four carboxyl­ate O atoms of four different pyridine-2,5-dicarboxyl­ate (2,5-pydc) ligands, and by the N atom of a...

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Autores principales: Zhang, Qing, Wang, Xing, Wang, Shen-Tang, Liu, Chun-Bo, Che, Guang-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344300/
https://www.ncbi.nlm.nih.gov/pubmed/22590066
http://dx.doi.org/10.1107/S160053681201286X
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author Zhang, Qing
Wang, Xing
Wang, Shen-Tang
Liu, Chun-Bo
Che, Guang-Bo
author_facet Zhang, Qing
Wang, Xing
Wang, Shen-Tang
Liu, Chun-Bo
Che, Guang-Bo
author_sort Zhang, Qing
collection PubMed
description In the title compound, {[Nd(3)(C(7)H(3)NO(4))(3)(OH)(3)]·H(2)O}(n), the Nd(III) atom is eight-coordinated by the three O atoms of three asymmetrically μ(3)-bridging hydroxide groups, by four carboxyl­ate O atoms of four different pyridine-2,5-dicarboxyl­ate (2,5-pydc) ligands, and by the N atom of a 2,5-pydc ligand. Six Nd atoms are connected by six hydroxide groups, forming an [Nd(6)(μ(3)-OH)(6)] cluster unit of symmetry -3 and a slightly compressed octa­hedral geometry. Adjacent [Nd(6)(μ(3)-OH)(6)] clusters are connected by the 2,5-pydc ligands, via O and N atoms, forming chains along the c axis. The remaining O atoms of the 2,5-pydc ligands link these chains into a three-dimensional framework. A disordered water molecule, located on a threefold rotation axis at the opposite side of the [Nd(6)(μ(3)-OH)(6)] cluster and exposed to each of the three Nd atoms, completes the structure.
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spelling pubmed-33443002012-05-15 Poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(III)] monohydrate] Zhang, Qing Wang, Xing Wang, Shen-Tang Liu, Chun-Bo Che, Guang-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Nd(3)(C(7)H(3)NO(4))(3)(OH)(3)]·H(2)O}(n), the Nd(III) atom is eight-coordinated by the three O atoms of three asymmetrically μ(3)-bridging hydroxide groups, by four carboxyl­ate O atoms of four different pyridine-2,5-dicarboxyl­ate (2,5-pydc) ligands, and by the N atom of a 2,5-pydc ligand. Six Nd atoms are connected by six hydroxide groups, forming an [Nd(6)(μ(3)-OH)(6)] cluster unit of symmetry -3 and a slightly compressed octa­hedral geometry. Adjacent [Nd(6)(μ(3)-OH)(6)] clusters are connected by the 2,5-pydc ligands, via O and N atoms, forming chains along the c axis. The remaining O atoms of the 2,5-pydc ligands link these chains into a three-dimensional framework. A disordered water molecule, located on a threefold rotation axis at the opposite side of the [Nd(6)(μ(3)-OH)(6)] cluster and exposed to each of the three Nd atoms, completes the structure. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344300/ /pubmed/22590066 http://dx.doi.org/10.1107/S160053681201286X Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Qing
Wang, Xing
Wang, Shen-Tang
Liu, Chun-Bo
Che, Guang-Bo
Poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(III)] monohydrate]
title Poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(III)] monohydrate]
title_full Poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(III)] monohydrate]
title_fullStr Poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(III)] monohydrate]
title_full_unstemmed Poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(III)] monohydrate]
title_short Poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(III)] monohydrate]
title_sort poly[[tri-μ(3)-hydroxido-tris­(μ(4)-pyridine-2,5-dicarboxyl­ato)trineodymium(iii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344300/
https://www.ncbi.nlm.nih.gov/pubmed/22590066
http://dx.doi.org/10.1107/S160053681201286X
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