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catena-Poly[[[aqua­[3-(3-hy­droxy­phen­yl)prop-2-enoato]samarium(III)]-bis­[μ(2)-3-(3-hy­droxy­phen­yl)prop-2-enoato]] monohydrate]

The title Sm(III) compound, {[Sm(C(9)H(7)O(3))(3)(H(2)O)]·H(2)O}(n), was obtained under hydrothermal conditions. Its structure is isotypic with the analogous Eu complex. The latter was reported incorrectly in space group P1 by Yan et al. [J. Mol. Struct. (2008), 891, 298–304]. This was corrected by...

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Detalles Bibliográficos
Autores principales: Guo, Jing-ke, Wen, Yi-Hang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344301/
https://www.ncbi.nlm.nih.gov/pubmed/22590067
http://dx.doi.org/10.1107/S1600536812013724
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author Guo, Jing-ke
Wen, Yi-Hang
author_facet Guo, Jing-ke
Wen, Yi-Hang
author_sort Guo, Jing-ke
collection PubMed
description The title Sm(III) compound, {[Sm(C(9)H(7)O(3))(3)(H(2)O)]·H(2)O}(n), was obtained under hydrothermal conditions. Its structure is isotypic with the analogous Eu complex. The latter was reported incorrectly in space group P1 by Yan et al. [J. Mol. Struct. (2008), 891, 298–304]. This was corrected by Marsh [Acta Cryst. B65, 782–783] to P-1. The Sm(III) ion is nine-coordinated by O atoms from one coordinating water molecule and the remaining ones from the 3-(3-hy­droxy­phen­yl)prop-2-enoatate anions (one bidentate, two bidentate and bridging, two monodentate bridging), leading to a distorted tricapped trigonal–prismatic coordination polyhedron surrounded by solvent water mol­ecules. In the crystal, extensive intermolecular O—H⋯O hydrogen-bonding inter­actions and π–π inter­actions [centroid–centroid separation = 3.9393 (1) Å] lead to the formation of a three-dimensional supra­molecular network.
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spelling pubmed-33443012012-05-15 catena-Poly[[[aqua­[3-(3-hy­droxy­phen­yl)prop-2-enoato]samarium(III)]-bis­[μ(2)-3-(3-hy­droxy­phen­yl)prop-2-enoato]] monohydrate] Guo, Jing-ke Wen, Yi-Hang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Sm(III) compound, {[Sm(C(9)H(7)O(3))(3)(H(2)O)]·H(2)O}(n), was obtained under hydrothermal conditions. Its structure is isotypic with the analogous Eu complex. The latter was reported incorrectly in space group P1 by Yan et al. [J. Mol. Struct. (2008), 891, 298–304]. This was corrected by Marsh [Acta Cryst. B65, 782–783] to P-1. The Sm(III) ion is nine-coordinated by O atoms from one coordinating water molecule and the remaining ones from the 3-(3-hy­droxy­phen­yl)prop-2-enoatate anions (one bidentate, two bidentate and bridging, two monodentate bridging), leading to a distorted tricapped trigonal–prismatic coordination polyhedron surrounded by solvent water mol­ecules. In the crystal, extensive intermolecular O—H⋯O hydrogen-bonding inter­actions and π–π inter­actions [centroid–centroid separation = 3.9393 (1) Å] lead to the formation of a three-dimensional supra­molecular network. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344301/ /pubmed/22590067 http://dx.doi.org/10.1107/S1600536812013724 Text en © Guo and Wen 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Jing-ke
Wen, Yi-Hang
catena-Poly[[[aqua­[3-(3-hy­droxy­phen­yl)prop-2-enoato]samarium(III)]-bis­[μ(2)-3-(3-hy­droxy­phen­yl)prop-2-enoato]] monohydrate]
title catena-Poly[[[aqua­[3-(3-hy­droxy­phen­yl)prop-2-enoato]samarium(III)]-bis­[μ(2)-3-(3-hy­droxy­phen­yl)prop-2-enoato]] monohydrate]
title_full catena-Poly[[[aqua­[3-(3-hy­droxy­phen­yl)prop-2-enoato]samarium(III)]-bis­[μ(2)-3-(3-hy­droxy­phen­yl)prop-2-enoato]] monohydrate]
title_fullStr catena-Poly[[[aqua­[3-(3-hy­droxy­phen­yl)prop-2-enoato]samarium(III)]-bis­[μ(2)-3-(3-hy­droxy­phen­yl)prop-2-enoato]] monohydrate]
title_full_unstemmed catena-Poly[[[aqua­[3-(3-hy­droxy­phen­yl)prop-2-enoato]samarium(III)]-bis­[μ(2)-3-(3-hy­droxy­phen­yl)prop-2-enoato]] monohydrate]
title_short catena-Poly[[[aqua­[3-(3-hy­droxy­phen­yl)prop-2-enoato]samarium(III)]-bis­[μ(2)-3-(3-hy­droxy­phen­yl)prop-2-enoato]] monohydrate]
title_sort catena-poly[[[aqua­[3-(3-hy­droxy­phen­yl)prop-2-enoato]samarium(iii)]-bis­[μ(2)-3-(3-hy­droxy­phen­yl)prop-2-enoato]] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344301/
https://www.ncbi.nlm.nih.gov/pubmed/22590067
http://dx.doi.org/10.1107/S1600536812013724
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AT wenyihang catenapolyaqua33hydroxyphenylprop2enoatosamariumiiibism233hydroxyphenylprop2enoatomonohydrate