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catena-Poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(III)]-bis[μ(2)-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate]
The title Sm(III) compound, {[Sm(C(9)H(7)O(3))(3)(H(2)O)]·H(2)O}(n), was obtained under hydrothermal conditions. Its structure is isotypic with the analogous Eu complex. The latter was reported incorrectly in space group P1 by Yan et al. [J. Mol. Struct. (2008), 891, 298–304]. This was corrected by...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344301/ https://www.ncbi.nlm.nih.gov/pubmed/22590067 http://dx.doi.org/10.1107/S1600536812013724 |
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author | Guo, Jing-ke Wen, Yi-Hang |
author_facet | Guo, Jing-ke Wen, Yi-Hang |
author_sort | Guo, Jing-ke |
collection | PubMed |
description | The title Sm(III) compound, {[Sm(C(9)H(7)O(3))(3)(H(2)O)]·H(2)O}(n), was obtained under hydrothermal conditions. Its structure is isotypic with the analogous Eu complex. The latter was reported incorrectly in space group P1 by Yan et al. [J. Mol. Struct. (2008), 891, 298–304]. This was corrected by Marsh [Acta Cryst. B65, 782–783] to P-1. The Sm(III) ion is nine-coordinated by O atoms from one coordinating water molecule and the remaining ones from the 3-(3-hydroxyphenyl)prop-2-enoatate anions (one bidentate, two bidentate and bridging, two monodentate bridging), leading to a distorted tricapped trigonal–prismatic coordination polyhedron surrounded by solvent water molecules. In the crystal, extensive intermolecular O—H⋯O hydrogen-bonding interactions and π–π interactions [centroid–centroid separation = 3.9393 (1) Å] lead to the formation of a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3344301 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33443012012-05-15 catena-Poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(III)]-bis[μ(2)-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate] Guo, Jing-ke Wen, Yi-Hang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Sm(III) compound, {[Sm(C(9)H(7)O(3))(3)(H(2)O)]·H(2)O}(n), was obtained under hydrothermal conditions. Its structure is isotypic with the analogous Eu complex. The latter was reported incorrectly in space group P1 by Yan et al. [J. Mol. Struct. (2008), 891, 298–304]. This was corrected by Marsh [Acta Cryst. B65, 782–783] to P-1. The Sm(III) ion is nine-coordinated by O atoms from one coordinating water molecule and the remaining ones from the 3-(3-hydroxyphenyl)prop-2-enoatate anions (one bidentate, two bidentate and bridging, two monodentate bridging), leading to a distorted tricapped trigonal–prismatic coordination polyhedron surrounded by solvent water molecules. In the crystal, extensive intermolecular O—H⋯O hydrogen-bonding interactions and π–π interactions [centroid–centroid separation = 3.9393 (1) Å] lead to the formation of a three-dimensional supramolecular network. International Union of Crystallography 2012-04-04 /pmc/articles/PMC3344301/ /pubmed/22590067 http://dx.doi.org/10.1107/S1600536812013724 Text en © Guo and Wen 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Guo, Jing-ke Wen, Yi-Hang catena-Poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(III)]-bis[μ(2)-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate] |
title |
catena-Poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(III)]-bis[μ(2)-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate] |
title_full |
catena-Poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(III)]-bis[μ(2)-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate] |
title_fullStr |
catena-Poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(III)]-bis[μ(2)-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate] |
title_full_unstemmed |
catena-Poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(III)]-bis[μ(2)-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate] |
title_short |
catena-Poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(III)]-bis[μ(2)-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate] |
title_sort | catena-poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(iii)]-bis[μ(2)-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344301/ https://www.ncbi.nlm.nih.gov/pubmed/22590067 http://dx.doi.org/10.1107/S1600536812013724 |
work_keys_str_mv | AT guojingke catenapolyaqua33hydroxyphenylprop2enoatosamariumiiibism233hydroxyphenylprop2enoatomonohydrate AT wenyihang catenapolyaqua33hydroxyphenylprop2enoatosamariumiiibism233hydroxyphenylprop2enoatomonohydrate |