trans-Carbonyl­chloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]rhodium(I)

In the title compound, trans-[RhCl(C(20)H(17)P)(2)(CO)], the Rh(I) atom is situated on a center of symmetry, resulting in a statistical 1:1 disorder of the chloride [Rh—Cl = 2.383 (2) Å] and carbonyl [Rh—C = 1.752 (7) Å] ligands. The distorted trans square-planar environment is completed by two P at...

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Detalles Bibliográficos
Autores principales: Ogutu, Hezron, Kirsten, Leo, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344302/
https://www.ncbi.nlm.nih.gov/pubmed/22590068
http://dx.doi.org/10.1107/S1600536812013669
Descripción
Sumario:In the title compound, trans-[RhCl(C(20)H(17)P)(2)(CO)], the Rh(I) atom is situated on a center of symmetry, resulting in a statistical 1:1 disorder of the chloride [Rh—Cl = 2.383 (2) Å] and carbonyl [Rh—C = 1.752 (7) Å] ligands. The distorted trans square-planar environment is completed by two P atoms [Rh—P = 2.3251 (4) Å] from two diphen­yl(4-vinyl­phen­yl)phosphane ligands. The vinyl group is disordered over two sets of sites in a 0.668 (10):0.332 (10) ratio. The crystal packing exhibits weak C—H⋯Cl and C—H⋯O hydrogen bonds and π–π inter­actions between the phenyl rings of neighbouring mol­ecules, with a centroid–centroid distance of 3.682 (2) Å.

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